Modified natural rubber masterbatch and method for producing the same as well as rubber composition and tire
AssigneeBridgestone Corporation
InventorHajime Kondou
Life of this patent
Estimating the term…
Abstract
This invention provides a method for producing a modified natural rubber masterbatch, which comprises the step of mixing a modified natural rubber latex, which is formed by adding a polar group-containing monomer to a natural rubber latex to graft-polymerize the polar group-containing monomer onto a natural rubber molecule in the natural rubber latex, with a slurry solution formed by previously dispersing a filler into water, and a modified natural rubber masterbatch produced by the method and capable of highly improving a low loss factor, a wear resistance and fracture characteristics of a rubber composition.
Claims14
A method for producing a modified natural rubber masterbatch, which comprises the step of mixing a modified natural rubber latex, which is formed by adding a polar group-containing monomer to a natural rubber latex to graft-polymerize the polar group-containing monomer onto a natural rubber molecule in the natural rubber latex, with a slurry solution formed by previously dispersing at least one filler selected from the group consisting of carbon black, silica and an inorganic compound represented by the following general formula (I):
- nM.xSiOy.zH2O (I)
- [wherein M is at least one selected from the group consisting of a metal of aluminum, magnesium, titanium, calcium or zirconium, oxides and hydroxides of these metals, their hydrates, and carbonates of these metals, n is an integer of 1-5, x is an integer of 0-10, y is an integer of 2-5, and z is an integer of 0-10] into water,
- wherein a grafting amount of the polar group-containing monomer is 0.01%-3.0% by mass based on a rubber component in the natural rubber latex.
Dependencies are inferred from the claim text.