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US 7,754,002 B2Granted
Solubility of cellulose in ionic liquids with addition of amino bases
AssigneeBASF SE
InventorsMatthias Maase, Veit Stegmann
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Abstract
The present invention relates to a solution comprising cellulose, an ionic liquid comprising anions and cations as solvent and 6-30% by weight of a nitrogen-comprising base, based on the total weight of the solution, its preparation and also its use for the physical or chemical treatment of cellulose.
Claims7
A solution comprising cellulose, an ionic liquid comprising anions and cations as solvent and 6-30% by weight of a nitrogen-comprising base, based on the total weight of the solution, wherein the ionic liquid comprises at least one cation of formula (IVe)
- and oligomers comprising these structures, where
- the radical R is hydrogen, a carbon-comprising organic, saturated or unsaturated, acyclic or cyclic, aliphatic, aromatic or araliphatic radical which has from 1 to 20 carbon atoms and is unsubstituted or interrupted by from 1 to 5 heteroatoms or functional groups or substituted;
- and
- the radicals R1 to R4 are each, independently of one another, hydrogen, a sulfo group or a carbon-comprising organic, saturated or unsaturated, acyclic or cyclic, aliphatic, aromatic or araliphatic radical which has from 1 to 20 carbon atoms and is unsubstituted or interrupted by from 1 to 5 heteroatoms or functional groups or substituted, with the radicals R1 to R4 which are bound to a carbon atom (and not to a heteroatom) in the abovementioned formulae (IV) also being able to be halogen or a functional group;
- or
- two adjacent radicals from the group consisting of R1 to R4 can together also be a divalent, carbon-comprising organic, saturated or unsaturated, acyclic or cyclic, aliphatic, aromatic or araliphatic radical which has from 1 to 30 carbon atoms and is unsubstituted or interrupted by from 1 to 5 heteroatoms or functional groups or substituted,
- wherein the nitrogen-comprising base is a compound whose nitrogen atom or atoms is/are primary, secondary or tertiary and which is derived from the quaternary compounds of formula (IVe), with the radical R forming the quaternary nitrogen of the quaternary compounds not being present and R1-R4, independently of one another, are as defined above.
4 more elements
Dependencies are inferred from the claim text.