# US 7,745,901 B1 · Highly-depleted laser doped semiconductor volume

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- Number: US 7,745,901 B1
- Document ID: US7745901B1
- Status: Granted
- Kind: B1
- Application number: 12/362,078
- Filed: 2009-01-29
- Granted: 2010-06-29
- Earliest claimed: 2009-01-29
- Assignees: SiOnyx, Inc.
- Inventors: Nathaniel J. McCaffrey; James E. Carey
- Web page: https://patentgrep.com/patent/US7745901B1

## CPC

- H10F 30/22: the devices having only one potential barrier, e.g. photodiodes
- H10F 30/21: the devices being sensitive to infrared, visible or ultraviolet radiation
- H10F 30/227: the potential barrier being a Schottky barrier
- H10F 71/00: Manufacture or treatment of devices covered by this subclass (patterning processes to connect thin photovoltaic cells in integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/33; manufacture or treatment of encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/80; manufacture or treatment of integrated devices, or assemblies of multiple devices, comprising at least one element in which radiation controls the flow of current H10F39/00)
- H10F 71/134: {Irradiation with electromagnetic or particle radiation}
- H10F: INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION

## Abstract

A device with increased photo-sensitivity using laser treated semiconductor as detection material is disclosed. In some embodiments, the laser treated semiconductor may be placed between and an n-type and a p-type contact or two Schottky metals. The field within the p-n junction or the Schottky metal junction may aid in depleting the laser treated semiconductor section and may be capable of separating electron hole pairs. Multiple device configurations are presented, including lateral and vertical configurations.

## Claims

### Claim 1

A photodiode, comprising:
an n-type section;
a p-type section;
a laser treated semiconductor section;
said laser treated semiconductor section disposed between said n-type section and said p-type section such that said n-type section and said p-type section can generate an electric field substantially capable of depleting at least a portion of said laser treated semiconductor section of free carriers and separating resulting electron-hole pairs generated in said laser treated semiconductor section.

### Claim 2 (depends on 1)

The photodiode of claim 1 wherein the laser treated semiconductor section comprises a net doped n-type material and the n-type section has a higher level of n-doping than the laser treated semiconductor section.

### Claim 3 (depends on 1)

The photodiode of claim 1 wherein the laser treated semiconductor section comprises a net doped p-type material and the p-type section has a higher level of p-doping than the laser treated semiconductor section.

### Claim 4 (depends on 1)

The photodiode of claim 1 further comprising a pair of electrical contact points, one on either side of said laser treated semiconductor section.

### Claim 5 (depends on 1)

The photodiode of claim 1 further comprising a substrate proximal to said laser treated semiconductor section and comprising at least a pair of electrical contact points, one proximal to a face of said laser treated semiconductor section and the other proximal to a face of said substrate opposing said face of said laser treated semiconductor section.

### Claim 6 (depends on 1)

The photodiode of claim 1 further comprising a substrate proximal to said laser treated semiconductor section and a plurality of electrical contact points disposed proximal to a face of said laser-treated semiconductor section.

### Claim 7 (depends on 6)

The photodiode of claim 6 wherein the n-type section partially encloses the p-type section and the laser treated semiconductor section.

### Claim 8 (depends on 6)

The photodiode of claim 6 wherein the p-type section partially encloses the n-type section and the laser treated semiconductor section.

### Claim 9

A photodiode comprising,
a first Schottky contact;
a second Schottky contact;
a laser treated semiconductor section;
said laser treated semiconductor being at least partially disposed between said first Schottky contact and said second Schottky contact;
said first Schottky contact having a higher work function than said second Schottky contact, such that said first Schottky contact and said second Schottky contact generate an electric field capable of substantially preventing electron-hole pairs generated by said laser treated semiconductor section from recombining in at least some portion of said laser treated semiconductor section.

### Claim 10 (depends on 9)

The photodiode of claim 9 said Schottky contacts comprising a pair of electrical contact points, one on either side of said laser treated semiconductor section.

### Claim 11 (depends on 9)

The photodiode of claim 9 further comprising a substrate proximal to said laser treated semiconductor section and said Schottky contacts comprising at least a pair of electrical contact points, one proximal to a face of said laser treated semiconductor section and the other proximal to a face of said substrate opposing said face of said laser treated semiconductor section.

### Claim 12 (depends on 9)

The photodiode of claim 9 further comprising a substrate proximal to said laser treated semiconductor section and said Schottky contacts providing a plurality of electrical contact points disposed proximal to a face of said laser-treated semiconductor section.

### Claim 13 (depends on 12)

The photodiode of claim 12 wherein said first Schottky contact partially encloses said second Schottky contact and said laser treated semiconductor section.

### Claim 14 (depends on 12)

The photodiode of claim 12 wherein said second Schottky contact partially encloses said first Schottky contact and said laser treated semiconductor section.

### Claim 15

A photodiode, comprising:
a first doped section;
a second doped section;
a laser treated semiconductor section;
said second doped section being substantially bounded by said first doped section, said laser treated semiconductor section being substantially bounded by said second doped section.

### Claim 16 (depends on 15)

The photodiode of claim 15 further comprising,
a first and a second contact;
said first contact being coupled to said first doped section, said second contact being coupled to said second doped section.

### Claim 17 (depends on 16)

The photodiode of claim 16 wherein said first doped section and said second doped section are substantially annular and said laser treated section is substantially disk shaped.

### Claim 18 (depends on 17)

The photodiode of claim 17 wherein said first doped section is n doped and said second doped section is p doped.

### Claim 19 (depends on 17)

The photodiode of claim 17 wherein said first doped section is p doped and said second doped section is n doped.

### Claim 20

A photodiode, comprising:
a first doped section comprising at least one subsection;
a second doped section comprising at least one subsection;
a laser treated semiconductor section;
a substrate comprising a first side;
said laser treated semiconductor section, said first doped section and said second doped section being disposed on said first side of said substrate, said second doped section being substantially bounded by said first doped section, said laser treated semiconductor section being substantially bounded by said second doped section.

### Claim 21 (depends on 20)

The photodiode of claim 20 wherein said second doped section comprises a first and a second subsection, said second doped section first and second subsections being disposed on either side of said laser treated semiconductor section.

### Claim 22 (depends on 21)

The photodiode of claim 21 wherein said first doped section comprises a first and a second subsection, said first doped section first and second subsections being disposed on the opposite side of said second doped section first and second subsections from said laser treated semiconductor section.

### Claim 23

A photodiode, comprising
a first doped section comprising at least one subsection;
a second doped section comprising at least one subsection;
a laser treated semiconductor section;
a substrate comprising a first and second side;
said laser treated semiconductor section and said first doped section being disposed on said first side of said substrate, said second doped section being disposed on said second side of said substrate, said laser treated semiconductor section being substantially bounded by said first doped section.

### Claim 24 (depends on 23)

The photodiode of claim 23 wherein said first doped section comprises a first and a second subsection being disposed on either side of said laser treated semiconductor section.
