# US 7,745,036 B2 · Direct oxidation fuel cell system and membrane electrode assembly thereof

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- Number: US 7,745,036 B2
- Document ID: US7745036B2
- Status: Granted
- Kind: B2
- Application number: 11/270,596
- Filed: 2005-11-10
- Published: 2007-05-10
- Granted: 2010-06-29
- Earliest claimed: 2005-11-10
- Assignees: Panasonic Corporation
- Inventors: Takashi Akiyama
- Web page: https://patentgrep.com/patent/US7745036B2

## CPC

- H01M 4/8636: {with a gradient in another property than porosity (H01M4/861 takes precedence)}
- H01M 4/926: {on carbon or graphite}
- H01M 8/1004: characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence)
- H01M 8/1011: Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
- H01M 4/921: {Alloys or mixtures with metallic elements}
- H01M 2008/1095: {Fuel cells with polymeric electrolytes}
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A membrane electrode assembly for a direct oxidation fuel cell includes a proton-conductive electrolyte membrane and an anode and a cathode sandwiching the electrolyte membrane. The equivalent weight of the proton-conductive substance contained in the catalyst layer of the anode is greater than the equivalent weight of the proton-conductive substance contained in the catalyst layer of the cathode. This invention reduces the performance deterioration caused by repetitive swelling and contraction of the electrolyte contained in the catalyst layer upon changes in operating conditions or upon repetitive start and stop of operation, thereby making it possible to provide a fuel cell with a high output and high performance.

## Claims

### Claim 1

A membrane electrode assembly for a direct oxidation fuel cell, said assembly comprising a proton-conductive electrolyte membrane and an anode and a cathode sandwiching said electrolyte membrane,
wherein said anode has an anode catalyst layer that comprises a first mixture of a first solid proton-conductive substance and a first catalyst,
said cathode has a cathode catalyst layer that comprises a second mixture of a second solid proton-conductive substance and a second catalyst, and
an equivalent weight EWa of the first proton-conductive substance contained in the anode catalyst layer of said anode is greater than an equivalent weight EWc of the second proton-conductive substance contained in the cathode catalyst layer of said cathode wherein the equivalent weight EWa of the first proton-conductive substance contained in the anode catalyst layer of said anode and the equivalent weight EWc of the second proton-conductive substance contained in the cathode catalyst layer of said cathode are 800 to 1200 g/Eq, and the difference between EWa and EWc is not less than 100 g/Eq.

### Claim 2 (depends on 1)

The membrane electrode assembly for a direct oxidation fuel cell in accordance with claim 1, wherein the first and second solid proton-conductive substances comprise a polymer comprising perfluorosulfonic acid.

### Claim 3

A direct oxidation fuel cell system, comprising:
at least one membrane electrode assembly comprising a proton-conductive electrolyte membrane, and an anode and a cathode sandwiching said electrolyte membrane, said assembly being sandwiched between an anode-side current collector plate and a cathode-side current collector plate;
a liquid fuel source in fluid communication with the anode of said at least one membrane electrode assembly; and
an oxidant source in fluid communication with the cathode of said at least one membrane electrode assembly,
wherein said anode has an anode catalyst layer that comprises a first mixture of a first solid proton-conductive substance and a first catalyst,
said cathode has a cathode catalyst layer that comprises a second mixture of a second solid proton-conductive substance and a second catalyst, and
an equivalent weight EWa of the first proton-conductive substance contained in the anode catalyst layer of said anode is greater than an equivalent weight EWc of the second proton-conductive substance contained in the cathode catalyst layer of said cathode wherein the equivalent weight EWa of the first proton-conductive substance contained in the anode catalyst layer of said anode and the equivalent weight EWc of the second proton-conductive substance contained in the cathode catalyst layer of said cathode are 800 to 1200 g/Eq, and the difference between EWa and EWc is not less than 100 g/Eq.

### Claim 4 (depends on 3)

The direct oxidation fuel cell system in accordance with claim 3, wherein the first and second solid proton-conductive substances comprise a polymer comprising perfluorosulfonic acid.

### Claim 5 (depends on 3)

The direct oxidation fuel cell system in accordance with claim 3, wherein said liquid fuel source includes methanol.