# US 7,744,955 B2 · Method of thermally tempering coated article with transparent conductive oxide (TCO) coating using flame(s) in tempering furnace adjacent TCO to burn off oxygen and product made using same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 7,744,955 B2 - Document ID: US7744955B2 - Status: Granted - Kind: B2 - Application number: 11/194,759 - Filed: 2005-08-02 - Published: 2007-02-08 - Granted: 2010-06-29 - Earliest claimed: 2005-08-02 - Assignees: Guardian Industries Corp. - Inventors: Richard Blacker; Cory Richardson; Alexey Krasnov - Web page: https://patentgrep.com/patent/US7744955B2 ## CPC - C03C 17/2453: {Coating containing SnO2} - C03C 17/245: by deposition from the vapour phase - C03C 2217/211: SnO2 - C03C 2217/214: Al2O3 - C03C 2217/216: ZnO - C03C 2217/24: Doped oxides - C03C 2217/256: Ag - C03C 2218/154: by sputtering - C03C 2218/32: After-treatment - C03C: CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS ## Abstract A method of making a coated article including a transparent conductive oxide (TCO) film supported by a glass substrate is provided. In certain example embodiments, the coated article including the TCO film on the glass substrate is thermally tempered in a tempering furnace. In certain example embodiments, during tempering flame(s) are provided proximate the exposed surface of the TCO in order to burn off excess oxygen near the TCO surface thereby preventing or reducing oxidation of the TCO during the tempering process. A coated article, that is thermally tempered, made by such a product is also provided. ## Claims ### Claim 1 A method of making a coated article including a transparent conductive film, the method comprising: providing a glass substrate; forming a film comprising a transparent conductive oxide on the glass substrate; and tempering the coated article including the glass substrate and the film comprising the transparent conductive oxide, and wherein at least one flame is provided in a tempering furnace in order to burn off oxygen to prevent or reduce oxidizing of the film comprising transparent conductive oxide during tempering, wherein the flame is provided in addition to another heating element which performs the tempering, so that the tempering occurs regardless of the flame. ### Claim 2 (depends on 1) The method of claim 1, wherein the flame is provided within 20 cm of an upper surface of the film comprising transparent conductive oxide, and wherein the film comprising the transparent conductive oxide has a sheet resistance of from about 5-100 ohms/square. ### Claim 3 (depends on 1) The method of claim 1, wherein a plurality of flames are provided in the tempering furnace. ### Claim 4 (depends on 1) The method of claim 1, wherein following tempering the film is still electrically conductive. ### Claim 5 (depends on 1) The method of claim 1, wherein at least part of the flame is located within about 10 cm of a surface of the film comprising transparent conductive oxide. ### Claim 6 (depends on 1) The method of claim 1, wherein at least part of the flame is located within about 5 cm of a surface of the film comprising transparent conductive oxide. ### Claim 7 (depends on 1) The method of claim 1, wherein at least part of the flame is located within about 2 cm of a surface of the film comprising transparent conductive oxide. ### Claim 8 (depends on 1) The method of claim 1, wherein at least part of the flame touches the film comprising transparent conductive oxide in the tempering furnace. ### Claim 9 (depends on 1) The method of claim 1, wherein no flame or flames is/are provided in a beginning portion of the tempering furnace. ### Claim 10 (depends on 9) The method of claim 9, wherein the beginning portion of the tempering furnace where no flame is provided is at least about 10% of the length of the tempering furnace. ### Claim 11 (depends on 9) The method of claim 9, wherein the beginning portion of the tempering furnace where no flame is provided is at least about 20% of the length of the tempering furnace. ### Claim 12 (depends on 1) The method of claim 1, wherein said forming the film comprising transparent conductive oxide on the glass substrate comprising sputtering at least one sputtering target at approximately room temperature so that no heaters are used when forming the film on the glass substrate. ### Claim 13 (depends on 1) The method of claim 1, wherein another layer is provided on the glass substrate so as to be located between the glass substrate and the film comprising transparent conductive oxide. ### Claim 14 (depends on 1) The method of claim 1, wherein the coated article has a visible transmission of at least about 50% before and/or after the tempering. ### Claim 15 A method of making a coated article including a transparent conductive film, the method comprising: providing a glass substrate; forming a transparent conductive film comprising a transparent conductive oxide on the glass substrate; and tempering the coated article including the glass substrate and the transparent conductive film, and wherein at least one flame is provided in a tempering furnace within about 20 cm of the transparent conductive film, wherein the flame, provided in order to burn off oxygen to prevent or reduce oxidizing of the film comprising transparent conductive oxide, is provided in addition to another heating element which performs the tempering, so that the tempering occurs regardless of the flame. ### Claim 16 (depends on 15) The method of claim 15, wherein the coated article has a visible transmission of at least about 50% before and/or after the tempering. ### Claim 17 (depends on 15) The method of claim 15, wherein the flame touches the transparent conductive film in the tempering furnace. ### Claim 18 (depends on 1) The method of claim 1, wherein the flame touches the film in the tempering furnace. ### Claim 19 (depends on 1) The method of claim 1, wherein the film comprising the transparent conductive oxide has a sheet resistance of no greater than about 200 ohms/square. ### Claim 20 (depends on 19) The method of claim 19, wherein the film comprising the transparent conductive oxide has a sheet resistance of no greater than about 100 ohms/square.