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US 7,732,648 B2Granted
Multistage catalytic process for olefin etherification
OwnerAmarjit Singh Bakshiinventor
Life of this patent
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Abstract
A process for producing ethers by reacting alcohols and olefins in successive catalytic stages is disclosed. The process includes alternating catalytic reaction stages and separation stages.
Claims2
A process for producing ethers, comprising:
- reacting iso-olefin with wet alcohol in a first catalytic reaction stage to provide a first reaction mixture;
- the first reaction mixture is sent to a first evaporation column for separating the first reaction mixture to provide a first light component fraction and a first heavy component fraction comprising ether;
- withdrawing a portion of the first light component fraction and reacting it in a second catalytic reaction stage to provide a second reaction mixture, which is recycled back to the first evaporation column;
- in the first evaporation column separating the second reaction mixture to provide a second light component fraction and a second heavy component fraction comprising ether;
- the first and second light component fractions exit the top of the column as a first overhead stream and the first and second heavy component fractions exit the bottom of the column as a first bottoms stream comprising ether and TBA;
- the first bottoms stream comprising ether and TBA is sent to a second evaporation column for separating the first bottoms stream to provide a second overhead stream comprising ether and a second bottoms stream comprising TBA;
- reacting the second bottoms stream comprising TBA in a catalytic reactor to generate an effluent comprising iso-olefin, which is recycled to the first catalytic reaction stage.
4 more elements
A process for producing ethers, comprising:
- reacting iso-olefin with wet alcohol in a first catalytic reaction stage to provide a first reaction mixture;
- the first reaction mixture is sent to a first evaporation column separating the first reaction mixture to provide a first light component fraction and a first heavy component fraction comprising ether;
- withdrawing a portion of the first light component fraction and reacting in a second catalytic reaction stage to provide a second reaction mixture, which is recycled back to the first evaporation column;
- in the first evaporation column separating in the second reaction mixture to provide a second light component fraction and a second heavy component fraction comprising ether, the first and second light component fractions exit the top of the column as a first overhead stream and the first and second heavy component fractions exit the bottom of the column as a first bottoms stream comprising ether and TBA;
- the first bottoms stream comprising ether and TBA is sent to a second evaporation column for separating the first bottoms stream to provide a second overhead stream comprising ether and a second bottoms stream comprising TBA;
- reacting the second bottoms stream with alcohol in a catalytic reactor to generate an effluent comprising ether;
- and recycling the effluent to the first evaporation column.
4 more elements
Dependencies are inferred from the claim text.