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US 7,732,554 B2Granted
Process for preparing a curable silylated polyurethane resin
AssigneeMomentive Performance Materials Inc.
InventorsBrendon J. O'Keefe, Holger J. Glatzer, Misty W. Huang, Christine Lacroix
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Abstract
The present invention relates to a process for the production of silylated polyurethane resins free of unreacted residual isocyanate possessing consistent viscosity and stability and products therefrom.
Claims24
A process for preparing a curable silylated polyurethane resin which comprises:
- a) silylating hydroxyl-terminated polyurethane polymer obtained from the reaction of polyol with di-isocyanate and/or polyisocyanate and optionally containing residual di-isocyanate and/or polyisocyanate with isocyanatosilane under anhydrous conditions to provide silylated polyurethane possessing residual hydroxyl groups and containing residual isocyanate selected from the group consisting of di-isocyanate, polyisocyanate and isocyanatosilane:
- and,
- b) scavenging residual isocyanate present in the silylated polyurethane with at least one isocyanate-reactive scavenging agent to provide silylated polyurethane resin of reduced isocyanate content,
- the silylated polyurethane resin of reduced isocyanate content resulting from step (b) possessing a viscosity following aging which is less than that of the isocyanate-containing silylated polyurethane resin resulting from step (a) following the same conditions of aging.
1 more element
Dependencies are inferred from the claim text.