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US 7,732,508 B2Granted
Automixable putty impression material
Assignee3M Espe AG
InventorsJoachim W. Zech, Peter Bissinger, Henning Hoffmann, Wolf Steiger
Life of this patent
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Abstract
The present invention relates to a multicomponent automixable putty impression material, its components, mixtures of the components and a method for obtaining impressions with the multicomponent automixable putty impression material.
Claims18
A composition comprising:
- a) at least one polydiorganosiloxane having at least two olefinically unsaturated groups as component (a),
- b) at least one organohydrogenpolysiloxane as component (b),
- c) at least one alkylsiloxane having at least one carbinol, carboxy or amino group as component (c),
- d) at least one condensation cure compound as component (d) and
- e) at least one addition cure precious metal catalyst as component (e);
- wherein component (c) contains at least one compound of the formula:
- R13Si—O—[SiR12—O—]aSiR12—Y—(O—R2)d—Xe—[(O—R2)b—OH]c (II) or
- [HO—(R2—O)b]c—Xe—(R2—O)d—Y—[SiR12—O—]aSiR12—Y—(O—R2)d—Xe—[(O—R2)b—OH]c (III) or
- R13Si—O—[SiR12—O—]aSiR12—Y—(O—R2)d—Xe-[Zf-COOH]c (IV) or
- [HOOC—Zf]c—Xe—(R2—O)d—Y—[SiR12—O—]aSiR12—Y—(O—R2)d—Xe-[Zf-COOH]c (V) or
- R13Si—O—{[SiR12—O—]n[SiR1(—Y—(O—R2)d—Xe-[Zf-COOH]c)—O—]m}—SiR13 (Va) or
- R13Si—O—[SiR12—O—]aSiR12—Y—(O—R2)d-Te-[(O—R2)b—NHR3]c (VI) or
- [R3HN—(R2—O)b]c-Te-(R2—O)d—Y—[SiR12—O—]aSiR12—Y—(O—R2)d-Te-[(O—R2)b—NHR3]c (VII) or
- R13Si—O—{[SiR12—O—]n[SiR4(—Y—(O—R2)d-Te-[(O—R2)b—NHR3]c)—O—]m}—SiR13 (VIIa) or
- wherein:
- X is a linear or branched hydrocarbon or an aryl residue that may contain an oxygen atom and/or an ether group with 6 to 14 C-atoms and a valency of c,
- Y is a linear or branched alkylene group with 1 to 10 C-atoms or a cycloalkyl group with 4 to 14 C-atoms,
- Z is a linear or branched alkylene or alkenylene or aryl group that may contain an ester group with 1 to 16 C-atoms,
- T is a linear or branched hydrocarbon or an aryl residue that may contain an oxygen atom and/or an ether group with 6 to 14 C-atoms and a valency of c,
- for formulas II, III, IIIb, VI, VII, VIIa, and VIIb, R1 is a linear or branched alkyl or fluoroalkyl group with 1 to 8 C-atoms or a cycloalkyl or aryl group with 6 to 14 C-atoms,
- for formulas IV, V, Va, and Vb, R1 is a linear or branched alkyl or fluoroalkyl group with 1 to 8 C-atoms or a cycloalkyl or aryl group with 4 to 14 C-atoms,
- R2 is a linear or branched alkylene group that may contain a carbonyl group with 1 to 8 C-atoms,
- D is R1 or —Y—(O—R2)d—Xe—[(O—R2)b—OH]c with at least one residue —Y—(O—R2)d—Xe—[(O—R2)b—OH]c per molecule,
- E is R1 or —Y—(O—R2)d—Xe-[Zf-COOH]c with at least one residue —Y—(O—R2)d—Xe-[Zf-COOH]c per molecule,
- F is R1 or —Y—(O—R2)d-Te-[(O—R2)b—NHR3]c with at least one residue —Y—(O—R2)d-Te-[(O—R2)b—NHR3]c per molecule,
- R3 is a linear or branched alkyl or fluoroalkyl group with 1 to 8 C-atoms or a cycloalkyl or aryl group with 6 to 14 C-atoms or H,
- R4 is R1 or methoxy or ethoxy,
- 1≦a≦10,000,
- for formulas II, III, IIIb, 0≦b≦500,
- for formulas VI, VII, VIIa, and VIIb, 0≦b≦10,000,
- 1≦c≦6,
- 0≦d≦500,
- e is 0 or 1,
- f is 0 or 1,
- 0≦n≦500 and 0≦m≦100 where m+n exceeds 5,
- x is 0, 1, 2, 3, 4, 5 or 6.
33 more elements
A two part system comprising parts A and B, wherein part A comprises:
- a) at least one polydiorganosiloxane having at least two olefinically unsaturated groups as component (a),
- b) at least one organohydrogenpolysiloxane as component (b), and
- c) at least one alkylsiloxane having at least one carbinol, carboxy or amino group as component (c), wherein component (c) contains at least one compound of the formula:
- R13Si—O—[SiR12—O—]aSiR12—Y—(O—R2)d—Xe—[(O—R2)b—OH]c (II) or
- [HO—(R2—O)b]c—Xe—(R2—O)d—Y—[SiR12—O—]aSiR12—Y—(O—R2)d—Xe—[(O—R2)b—OH]c (III) or
- R13Si—O—{[SiR12—O—]n[SiR1(—Y—(O—R2)d—Xe—[(O—R2)b—OH]c)—O—]m}—SiR13 (IIIa) or
- R13Si—O—[SiR12—O—]aSiR12—Y—(O—R2)d—Xe-[Zf-COOH]c (IV) or
- [HOOC—Zf]c—Xe—(R2—O)d—Y—[SiR12—O—]aSiR12—Y—(O—R2)d—Xe-[Zf-COOH]c (V) or
- R13Si—O—{[SiR12—O—]n[SiR1(—Y—(O—R2)d—Xe-[Zf-COOH]c)—O—]m}—SiR13 (Va) or
- R13Si—O—[SiR12—O—]aSiR12—Y—(O—R2)d-Te-[(O—R2)b—NHR3]c (VI) or
- [R3HN—(R2—O)b]c-Te-(R2—O)d—Y—[SiR12—O—]aSiR12—Y—(O—R2)d-Te-[(O—R2)b—NHR3]c (VII) or
- R13Si—O—{[SiR12—O—]n[SiR4(—Y—(O—R2)d-Te-[(O—R2)b—NHR3]c)—O—]m}—SiR13 (VIIa) or
- wherein:
- X is a linear or branched hydrocarbon or an aryl residue that may contain an oxygen atom and/or an ether group with 6 to 14 C-atoms and a valency of c,
- Y is a linear or branched alkylene group with 1 to 10 C-atoms or a cycloalkyl group with 4 to 14 C-atoms,
- Z is a linear or branched alkylene or alkenylene or aryl group that may contain an ester group with 1 to 16 C-atoms,
- T is a linear or branched hydrocarbon or an aryl residue that may contain an oxygen atom and/or an ether group with 6 to 14 C-atoms and a valency of c,
- for formulas II, III, IIIa, IIIb, VI, VII, VIIa, and VIIb, R1 is a linear or branched alkyl or fluoroalkyl group with 1 to 8 C-atoms or a cycloalkyl or aryl group with 6 to 14 C-atoms,
- for formulas IV, V, Va, and Vb, R1 is a linear or branched alkyl or fluoroalkyl group with 1 to 8 C-atoms or a cycloalkyl or aryl group with 4 to 14 C-atoms,
- R2 is a linear or branched alkylene group that may contain a carbonyl group with 1 to 8 C-atoms,
- D is R1 or —Y—(O—R2)d—Xe—[(O—R2)b—OH]c with at least one residue —Y—(O—R2)d—Xe—[(O—R2)b—OH]c per molecule,
- E is R1 or —Y—(O—R2)d—Xe-[Zf-COOH]c with at least one residue —Y—(O—R2)d—Xe-[Zf-COOH]c per molecule,
- F is R1 or —Y—(O—R2)d-Te-[(O—R2)b—NHR3]c with at least one residue —Y—(O—R2)d-Te-[(O—R2)b—NHR3]c per molecule,
- R3 is a linear or branched alkyl or fluoroalkyl group with 1 to 8 C-atoms or a cycloalkyl or aryl group with 6 to 14 C-atoms or H,
- R4 is R1 or methoxy or ethoxy,
- 1≦a≦10,000,
- for formulas II, III, IIIa, IIIb, 0≦b≦500,
- for formulas VI, VII, VIIa, and VIIb, 0≦b≦10,000,
- 1≦c≦6,
- 0≦d≦500,
- e is 0 or 1,
- f is 0 or 1,
- 0≦n≦500 and 0≦m≦100 where m+n exceeds 5,
- x is 0, 1, 2, 3, 4, 5 or 6
- and part B comprises:
- d) at least one condensation cure component as component (d) and
- e) at least one addition cure precious metal catalyst as component (e).
34 more elements
Dependencies are inferred from the claim text.