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US 7,731,838 B2Granted
Solid acid assisted deep desulfurization of diesel boiling range feeds
AssigneeExxonMobil Research and Engineering Company
InventorsJonathan M. McConnachie, Catalina L. Coker, Madhav Acharya
Life of this patent
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Abstract
The instant invention relates to a process to produce low sulfur diesel products through the hydrodesulfurization of low nitrogen diesel boiling range feedstreams in the presence of solid acidic materials.
Claims20
A process for producing low sulfur diesel boiling range product comprising:
- (a) contacting a diesel boiling range feedstream having a boiling range of from about 451° F. to about 800° F., the feedstream containing organically bound sulfur molecules and nitrogen-containing compounds, with a material in a contacting stage operated under conditions effective at removing at least a portion of said nitrogen-containing compounds in said diesel boiling range feedstream thereby producing at least a contacting stage effluent comprising at least a diesel boiling range effluent containing organically bound sulfur molecules and having a reduced amount of nitrogen-containing compounds;
- and
- (b) contacting at least a portion of said contacting stage effluent
- (i) in a first reaction stage operated under conditions effective at isomerizing at least a portion of said organically bound sulfur molecules with a first catalyst comprising at least one solid acidic component having an alpha value in the range of about 1 to about 50 thereby producing at least a first reaction stage effluent;
- and
- (ii) in the presence of hydrogen-containing treat gas, in a second reaction stage operated under effective hydrotreating conditions with a second catalyst selected from hydrotreating catalysts comprising at least one Group VIII metal oxide and at least one Group VI metal oxide thereby producing at least a desulfurized diesel boiling range product stream.
3 more elements
A process for producing low sulfur diesel products comprising:
- (a) contacting a feedstream that includes 600° F.+ boiling compounds, has an initial boiling point of at least about 400° F., and has an end boiling point of about 800° F. or less, and that also contains organically bound sulfur molecules in the form of sterically hindered dibenzothiophenes and nitrogen-containing compounds, with a material in a contacting stage operated under conditions effective at removing at least a portion of said nitrogen-containing compounds in said feedstream thereby producing at least a contacting stage effluent containing organically bound sulfur molecules and having a reduced amount of nitrogen-containing compounds;
- (b) contacting at least a portion of said contacting stage effluent in a first reaction stage operated under conditions effective at isomerizing at least a portion of said organically bound sulfur molecules with a first catalyst comprising at least one solid acidic component having an alpha value in the range of about 1 to about 50 thereby producing at least a first reaction stage effluent;
- and
- (c) contacting, in the presence of hydrogen-containing treat gas, at least a portion of the first reaction stage effluent of step b) above in a second reaction stage operated under effective hydrotreating conditions with a second catalyst selected from hydrotreating catalysts comprising at least one Group VIII metal oxide and at least one Group VI metal oxide thereby producing at least a desulfurized diesel boiling range product stream.
1 more element
Dependencies are inferred from the claim text.