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US 7,726,127 B2Granted
Solar power for thermochemical production of hydrogen
AssigneePratt & Whitney Rocketdyne, Inc.
InventorsRobert Z. Litwin, Stanley M. Pinkowski
Life of this patent
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Abstract
A solar-powered hydrogen production system includes a thermochemical system and solar heating system. The thermochemical system produces hydrogen. The solar heating system has a molten salt heat transfer medium for providing thermal energy to the thermochemical system.
Claims16
A solar-powered hydrogen production system, the system comprising:
- a low temperature thermochemical system using a copper chloride thermochemical cycle for producing hydrogen with a maximum reaction temperature of about 530° C.;
- and
- a solar heating system having a molten salt heat transfer medium for providing thermal energy to the thermochemical system;
- wherein the copper chloride thermochemical cycle for producing hydrogen comprises the following set of chemical reactions and reaction temperatures:
- 2Cu(s)+2HCl(l)=2CuCl(l)+H2(g) at a temperature of between about 430° C. to about 475° C.;
- 2CuCl(s)=2CuCl2(aq)+2Cu at a temperature of between about 25° C. to about 75° C.;
- 2CuCl2(s)+H2O(g)=CuO*CuCl2(s)+2HCl(g) at a temperature of between about 350° C. to 400° C.;
- and
- CuO*CuCl2(s)=2CuCl(l)+½O2(g) at a temperature of about 530° C.
6 more elements
A system comprising:
- a low temperature thermochemical system using a copper chloride thermochemical cycle for producing hydrogen with a maximum reaction temperature of about 530° C.;
- a molten salt heat transfer medium for providing thermal energy to the low temperature thermochemical system;
- and
- a solar receiver for heating the heat transfer medium;
- wherein the copper chloride thermochemical cycle for producing hydrogen comprises the following set of chemical reactions and reaction temperatures:
- 2Cu(s)+2HCl(l)=2CuCl(l)+H2(g) at a temperature of between about 430° C. to about 475° C.;
- 2CuCl(s)=2CuCl2(aq)+2Cu at a temperature of between about 25° C. to about 75° C.;
- 2CuCl2(s)+H2O(g)=CuO*CuCl2(s)+2HCl(g) at a temperature of between about 350° C. to 400° C.;
- and
- CuO*CuCl2(s)=2CuCl(l)+½O2(g) at a temperature of about 530° C.
7 more elements
A method comprising:
- capturing solar energy from sunlight;
- heating a heat transfer medium with the solar energy;
- transporting the heat transfer medium to a hydrogen and oxygen production system;
- and
- generating hydrogen and oxygen with the hydrogen and oxygen production system with a maximum reaction temperature of about 530° C.;
- wherein the hydrogen and oxygen production system is a copper chloride thermochemical cycle comprising the following set of chemical reactions and reaction temperatures:
- 2Cu(s)+2HCl(l)=2CuCl(l)+H2(g) at a temperature of between about 430° C. to about 475° C.;
- 2CuCl(s)=2CuCl2(aq)+2Cu at a temperature of between about 25° C. to about 75° C.;
- 2CuCl2(s)+H2O(g)=CuO*CuCl2(s)+2HCl(g) at a temperature of between about 350° C. to 400° C.;
- and
- CuO*CuCl2(s)=2CuCl(l)+½O2(g) at a temperature of about 530° C.
8 more elements
Dependencies are inferred from the claim text.