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US 7,691,290 B2Granted
Oxygen scavenging compositions and packaging comprising said compositions
AssigneeConstar International Inc.
InventorsGirish Nilkanth Deshpande, Venkat Govindarajan, John Rost, Alan Silverman
Life of this patent
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Abstract
The instant invention concerns a composition comprising a base polymer, at least one compound of the formula E-(L-E)x wherein: E is and L is a linking group; and at least one transition metal in a positive oxidation state. The invention also concerns packages containing walls comprising such compositions, methods of forming such packages, and methods of packaging an oxygen-sensitive item within such a package.
Claims15
A composition comprising:
- (a) at least one base polymer comprising a polyester polymer;
- (b) at least one non-polymeric oxidizable organic component present in an amount of about 0.10 to 10 weight present of the composition and the component comprising at least one compound of the formula E-(L-E)x wherein:
- E is
- L is a linking group of the formula —(O—R21)z—O—, —(NH—R21)z—NH—, —(NH—C(═O)R22)t—NH, —NH—R25—NH(C(═O)R26NHR25NH)u—, —(O—R23—O—R24—C(═O)s—O— where L is attached to a carbon atom of Ar in structure (I) L;
- x is 0, 1, or 2;
- Ar is aryl or heteroaryl;
- R1 and R2 are each independently, H, C1-C12 alkyl, C1-C6 alkoxy, C6-C20 aryloxy, hydroxy, C2-C6 alkenyl, NR19R20, acetyl, nitro, glyceryl, carbohydrate, —C(═O)H, L, or two R1 or two R2 groups form a group of the formula —O—R18—O;
- R3 and R4 are each H;
- R5 to R10 are each, independently, H or C1-C3 alkyl;
- R18 is C2-C6 alkyl;
- R19 and R20 are each, independently, H, C1-C6 alkyl, or C6-C20 aryl;
- R21 and R24 are each, independently, C1-C6 alkyl;
- R22, R23, R25 and R26 are each, independently, C1-C6 alkyl or C6-C20 aryl;
- n and p are independently 0 or an integer from 1 to 5;
- s and z are, independently 1, 2, or 3;
- t and u are, independently 1 or 2;
- and
- (c) at least one transition metal in a positive oxidation state, the metal being present in the composition in an amount of 10 to 400 ppm.
15 more elements
A process for making an article comprising:
- (a) forming a melt by combining the following ingredients in a melt processing zone:
- (i) at least one base polymer comprising a polyester polymer,
- (ii) at least one non-polymeric oxidizable organic component present in an amount of about 0.10 to 10 weight present of the composition and the component comprising at least one compound of the formula E-(L-E)x wherein:
- E is
- L is a linking group of the formula —(O—R21)z—O—, —(NH—R21)z—NH—, —(NH—C(═O)R22)t—NH, —NH—R25—NH(C(═O)R26NHR25NH)u—, —(O—R23—O—R24—C(═O)s—O— where L is attached to a carbon atom of Ar in structure (I);
- x is 0, 1, or 2;
- Ar is aryl or heteroaryl;
- R1 and R2, are each independently, H, C1-C12 alkyl, C1-C6 alkoxy, C6-C20 aryloxy, hydroxy, C2-C6 alkenyl, NR19R20, acetyl, nitro, glyceryl, carbohydrate, —C(═O)H, L, or two R1 or two R2 groups form a group of the formula —O—R18—O;
- R3 and R4 are each H;
- R5 to R10 are each, independently, H or C1-C3 alkyl;
- R18 is C2-C6 alkyl;
- R19 and R20 are each, independently, H, C1-C6 alkyl, or C6-C20 aryl;
- R21 and R24 are each, independently, C1-C6 alkyl;
- R22, R23, R25 and R26 are each, independently, C1-C6 alkyl or C6-C20 aryl;
- n and p are independently 0 or an integer from 1 to 5;
- s and z are, independently 1, 2, or 3;
- t and u are, independently 1 or 2;
- and
- (iii) at least one transition metal in a positive oxidation state, the metal being present in the composition in an amount of 10 to 400 ppm;
- (b) forming an article from the melt.
17 more elements
Dependencies are inferred from the claim text.