Silver β-ketocarboxylate, material comprising the same for forming silver metal, and use thereof
AssigneesOsaka Industrial Promotional Organization, Osaka University
InventorsKatsuaki Suganuma, Shunro Yamaguchi, Mariko Hatamura
Life of this patent
Estimating the term…
Abstract
It is an object to provide a novel material that can quickly form metal silver even at a low temperature of approximately 210° C. or less. This serves as a metal silver forming material that includes a silver β-ketocarboxylate. By heating this forming material, it is possible to form metal silver quickly even at a low temperature of approximately 210° C. or less. Examples of the silver β-ketocarboxylate include silver isobutyrylacetate, silver benzoylacetate, silver acetoacetate, silver propionylacetate, silver α-methylacetoacetate, and silver α-ethylacetoacetate.
Claims23
A silver β-ketocarboxylate represented by Formula (1) below:
- wherein in Formula (1), R is a straight, branched or cyclic saturated or unsaturated C1 to C20 aliphatic hydrocarbon group, R1—CY2—, CY3—, R1—CHY—, R2O—, a phenyl group, a phenyl group with one or more substituent groups, R5R4N—, a hydroxyl group (—OH), an amino group (—NH2), or (R3O)2CY—;
- wherein the Y groups are identical or different, and each is a fluorine atom, a chlorine atom, a bromine atom, or a hydrogen atom, R1 is a straight, branched or cyclic saturated or unsaturated C1 to C19 aliphatic hydrocarbon group, or a phenyl group, R2 is a straight, branched or cyclic saturated or unsaturated C1 to C20 aliphatic hydrocarbon group, R3 is a straight, branched or cyclic saturated or unsaturated C1 to C16 aliphatic hydrocarbon group, and R4 and R5 are identical or different, and each is a straight, branched or cyclic saturated or unsaturated C1 to C18 aliphatic hydrocarbon group;
- wherein in Formula (1), the X groups are identical or different, and each is a hydrogen atom, a straight, branched or cyclic saturated or unsaturated C1 to C20 aliphatic hydrocarbon group, R6O—, R6S—, R6—CO—, R6—CO—O—, a halogen (fluorine, chlorine, bromine, iodine), a benzyl group, a phenyl group, a phenyl group or a benzyl group that has one or more substituent groups, a cyano group (—C≡N), a N-phthaloyl-3-aminopropyl group, or a 2-ethoxyvinyl group (C2H5—O—CH═CH—);
- and
- wherein R6 is a straight, branched or cyclic saturated or unsaturated C1 to C10 aliphatic hydrocarbon group, a thiophene group (C4H3S—), a phenyl group, a diphenyl group, or a phenyl group or a diphenyl group that has one or more substituent groups.
A material for forming metal silver that includes silver β-ketocarboxylate.
A method of producing silver β-ketocarboxylatc, comprising:
- a step of reacting a β-ketocarboxylic acid and a silver compound in a reaction solution whose water content is not more than 55 wt %, to form a silver β-ketocarboxylate.
Dependencies are inferred from the claim text.