Process of producing lithium metal composite oxide particles
AssigneeCanon Kabushiki Kaisha
InventorsKatsuhiko Inoue, Soichiro Kawakami
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Abstract
There is provided a lithium secondary battery having a high capacity and excellent high-rate discharge characteristic and charge/discharge cycle characteristic. The lithium secondary battery comprises a negative electrode, a positive electrode and an ionic conductor, wherein the positive electrode comprises lithium metal composite oxide particles; the lithium metal composite oxide particles comprise a plurality of secondary particles in an elongated shape each comprised of a plurality of primary particles with an average particle size of 0.1 to 1 μm so aggregated as to form a void therebetween; and the secondary particle is columnar or planar and has an average size in a long length direction of 5 to 15 μm.
Claims15
A process of producing lithium metal composite oxide particles which electrochemically intercalate and deintercalate lithium ions, the lithium metal composite oxide particles comprising a plurality of secondary particles in an elongated shape each comprised of a plurality of primary particles with an average particle size of 0.1 μm to 1 μm so aggregated as to form voids therebetween, wherein the plurality of secondary particles have an average size in a long length direction of 5 μm to 15 μm, and wherein each of the plurality of secondary particles has a columnar shape or a planar shape, said process comprising:
- (1) mixing a cobalt-salt containing aqueous solution, a surfactant and unsubstituted or substituted urea to prepare a mixed solution;
- (2) heating the mixed solution or adding an alkali component to the mixed solution to raise the pH value of the mixed solution, thereby depositing a cobalt-containing compound;
- (3) mixing a lithium-containing material with the deposited cobalt-containing compound or a cobalt-containing oxide obtained by heat-treating the deposited cobalt-containing compound to prepare a mixture;
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- (4) calcining the mixture in air or oxygen.
Dependencies are inferred from the claim text.