Method for producing halogen-substituted benzenedimethanol
AssigneeSumitomo Chemical Company, Limited
InventorKoji Hagiya
Life of this patent
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Abstract
A method for producing a halogen-substituted benzenedimethanol represented by the formula (2): wherein X1 to X4 are the same or different and independently represent a halogen atom or the like, provided that at least one of X1 to X4 is a halogen atom, by reacting a halogen-substituted terephthalic acid diester represented by the formula (1): wherein R1 and R2 are the same or different and independently represent a C1-C20 alkyl group which may have a substitutent or substituents, and X1 to X4 is the same as defined above, with a borohydride compound in the presence of an alcohol which comprises adding the alcohol into a mixture of the halogen-substituted terephthalic acid diester represented by the formula (1), the borohydride compound and a solvent.
Claims8
A method for producing a halogen-substituted benzenedimethanol represented by the formula (2):
- wherein X1 to X4 are the same or different and independently represent a hydrogen or halogen atom, provided that at least one of X1 to X4 is a halogen atom,
- by reacting a halogen-substituted terephthalic acid diester represented by the formula (1):
- wherein R1 and R2 are the same or different and independently represent an optionally substituted C1-C20 alkyl group and the substituent of the alkyl group is a fluorine atom;
- a C1-C20 alkoxy group which is optionally substituted with a halogen atom or atoms;
- a C6-C20 aryl group which is optionally substituted with a C1-C6 alkoxy group or groups;
- a C6-C20 aryloxy group which is optionally substituted with a C1-C6 alkoxy group or groups or phenoxy group or groups;
- or a C7-C20 aralkyloxy group which is optionally substituted with a C1-C6 alkoxy group or groups or phenoxy group or groups, and X1 to X4 is the same as defined above,
- with a borohydride compound in the presence of an alcohol which comprises adding the alcohol into a mixture of the halogen-substituted terephthalic acid diester represented by the formula (1), the borohydride compound and a solvent.
Dependencies are inferred from the claim text.