Method for producing polycarbonate copolymer and polycarbonate copolymer
AssigneeIdemitsu Kosan Co., Ltd.
InventorsKoichi Suga, Yasuhiro Ishikawa
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Abstract
A method for producing a PC copolymer with improved productivity is provided. The PC copolymer has a specific structure and the method uses a diester diol-containing monomer as a raw material. The polycarbonate copolymer is produced by reacting a diester diol-containing monomer, a divalent phenol, and a carbonate precursor by interfacial polymerization, wherein the diester diol-containing monomer is a product of reaction between a hydroxybenzoic acid or an esterified product thereof and a polyalkylene glycol, wherein the esterification degree of hydroxyl groups of the polyalkylene glycol is 50 to 90 mol %.
Claims7
A method for producing a polycarbonate copolymer comprising repeating units represented by the following formulas (I) and (II):
- where:
- R1 and R2 are each independently a halogen atom or an alkyl group having 1 to 6 carbon atoms;
- when there are two or more R1s, each R1 can be different from or the same as the other(s);
- when there are two or more R2s, each R2 can be different from or the same as the other(s);
- a and b are each independently an integer from 0 to 4;
- and
- X represents a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycle alkylidene group having 5 to 15 carbon atoms, —S—, —SO—, —SO2—, —O—, —CO—, or a bond represented by the following formula (III-1) or (III-2):
- where:
- R is an alkyl group having 1 to 3 carbon atoms;
- Y is a straight chain or branched alkylene group having 2 to 15 carbon atoms;
- m is an integer of 0 to 4;
- and
- r is an integer of 2 to 450;
- the method comprising:
- reacting a diester diol-containing monomer, a divalent phenol, and a carbonate precursor by interfacial polymerization, wherein;
- the diester diol-containing monomer is a mixture of a diester diol according to the following formula (3) and a monoester diol represented by the following formula (4)
- the mixture is obtained by reaction of a hydroxybenzoic acid or an esterified product thereof represented by the following formula (1) and a polyalkylene glycol represented to by the following formula (2):
- where R′ is a hydrogen or a lower alkyl group;
- an esterification degree of hydroxyl groups of the polyalkylene glycol is 50 to 90 mol %.
Dependencies are inferred from the claim text.