1-phenyl-3-piperazine-pyrazoles and pesticidal compositions of matter thereof

5-diazacycloalkylpyrazole derivatives of formula (I):

• wherein:
• R1 is CN, CH3, CF3, C(═N-Z)—S(O)p—(C1-C4)-alkyl or CSNH2;
• wherein Z is H, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C3-C6)-alkenyl, (C3-C6)-alkynyl, —(CH2)qR8, COR9, CO2—(C1-C6)-alkyl;
• or S(O)pR9
• R2 is halogen, CH3 or NR11R12;
• R3 is (C1-C3)-haloalkyl, (C1-C3)-haloalkoxy or SF5;
• R4 (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, CO2—(C1-C6)-alkyl, CO2—(C3-C6)-alkenyl, CO2—(C3-C6)-alkynyl, CO2—(CH2)qR8, CO2—(CH2)qR10, CONR6R7 or SO2R9;
• formyl, COCO2-(C1-C6)-alkyl or CO2—(C1-C6)-alkyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, (C3-C6)-alkenyloxy, (C3-C6)haloalkenyloxy, (C3-C6)-alkynyloxy, (C3-C6)-haloalkynyloxy, (C3-C7)cycloalkyl, S(O)pR9, CN, NO2, OH, R8, R10, COR9, NR6R7, OR9 and CO2R9;
• or CO—(CH2)mR8;
• or CO—(CH2)mR10;
• or (C1-C6)-alkyl substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, (C3-C6)-alkenyloxy, (C3-C6)-haloalkenyloxy, (C3-C6)alkynyloxy, (C3-C6)-haloalkynyloxy, S(O)pR9, CN, NO2, OH, R10, COR9, NR6R7, OR9, COOH and CO2R9;
• or R8 and R10;
• R5 is (C1-C6)-alkyl, or(C1-C6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl,(C2-C6)-alkynyl or (C2-C6)-haloalkynyl;
• A is (C1-C6)-alkylene or (C2-C6)-alkenylene which groups are unsubstituted or substituted by one or more (C1-C6)-alkyl, (C1-C6)-haloalkyl;
• —COCH2—;, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkyl-(C1-C4)-alkyl,(CH2)qR8 or (CH2)qR10
• E is (C2-C6)-alkylene or (C2-C6)-alkenylene which groups are unsubstituted or substituted by one or more (C1-C6)-alkyl, (C1-C6)-haloalkyl;, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkyl-(C1C4)-alkyl, (CH2)qR8 or (CH2)qR10;
• R6 and R7 is each independently H, (C1-C6)-alkyl, (C1-C6)-haloalkyl , (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C7)-cycloalkyl, (C3-C7)-cycloalkyl-(C1-C4)-alkyl, (CH2)qR8 or (CH2)qR10;
• or
• R6 and R7 may be formed together with the attached N atom a four- to seven-membered saturated ring or a five- to seven-membered unsaturated ring, which ring optionally contains one or more additional hetero atoms in the ring which are selected from 0, S and N;
• R8 is phenyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, CN, NO2, S(O)pR9 and NR6R7;
• R9 is (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C3-C7)-cycloalkyl, -(C1-C4)-alkyl-(C3-C7)-cycloalkyl, (CH2)qR8 or (CH2)qR10;
• R10 is heterocyclyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C4)-alkyl, (C1-C4)-haloalkyl, (C1-C4)-alkoxy, S(O)pR9, OH and oxo;
• R11 and R12 are each independently H, (C1-C6)-alkyl, (C2-C6)-alkenyl or (C2-C6)-alkynyl, which last three mentioned groups are unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C3-C7)-cycloalkyl, R8, R10, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy;
• n, p and q are each independently zero, one or two;
• m is zero, one, two or three;
• and
• each heterocyclyl in the above-mentioned radicals is independently a heterocyclic radical having 3 to 7 ring atoms and 1, 2 or 3 hetero atoms in the ring selected from the group consisting of N, O and S;
• or a pesticidally acceptable salt thereof.