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US 7,678,505 B2Granted
Organic electrolytic solution and lithium battery employing the same
AssigneeSamsung SDI Co., Ltd.
InventorsSeok-soo Lee, Young-gyoon Ryu, Han-su Kim
Life of this patent
Estimating the term…
Abstract
An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes: a lithium salt; an organic solvent containing a high dielectric constant solvent and a low boiling point solvent; and an additive comprising a crotonate derivative including a substituted silyl group. The organic electrolytic solution and the lithium battery employing such an electrolytic solution suppress a reduction decomposition of a polar solvent and decrease irreversible capacity in the first cycle. Thus, the charge/discharge efficiency, lifespan, and reliability of the battery can be improved.
Claims18
An organic electrolytic solution comprising:
- a lithium salt;
- an organic solvent comprising a high dielectric constant solvent and a low boiling point solvent;
- and a compound represented by formula (1):
- where:
- R1 is selected from the group consisting of a hydrogen atom, a substituted or unsubstituted alkyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having from 6 to 30 carbon atoms, a substituted or unsubstituted aryloxy group having from 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having from 2 to 30 carbon atoms, and a substituted or unsubstituted heteroaryloxy group having from 2 to 30 carbon atoms;
- R2 and R3 are each independently selected from the group consisting of a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having from 6 to 30 carbon atoms, a substituted or unsubstituted aryloxy group having from 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having from 2 to 30 carbon atoms, and a substituted or unsubstituted heteroaryloxy group having from 2 to 30 carbon atoms;
- and
- R4, R5 and R6 are each independently selected from the group consisting of a hydrogen atom, a halogen atom, a hydroxyl group, a substituted or unsubstituted alkyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having from 6 to 30 carbon atoms, a substituted or unsubstituted aryloxy group having from 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having from 2 to 30 carbon atoms, and a substituted or unsubstituted heteroaryloxy group having from 2 to 30 carbon atoms.
5 more elements
A lithium battery comprising a cathode, an anode, a lithium salt;
- and an electrolytic solution comprising:
- an organic solvent comprising a high dielectric constant solvent and a low boiling point solvent;
- and
- a compound represented by formula (1):
- where:
- R1 is selected from the group consisting of a hydrogen atom, a substituted or unsubstituted alkyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having from 6 to 30 carbon atoms, a substituted or unsubstituted aryloxy group having from 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having from 2 to 30 carbon atoms, and a substituted or unsubstituted heteroaryloxy group having from 2 to 30 carbon atoms;
- R2 and R3 are each independently selected from the group consisting of a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having from 6 to 30 carbon atoms, a substituted or unsubstituted aryloxy group having from 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having from 2 to 30 carbon atoms, and a substituted or unsubstituted heteroaryloxy group having from 2 to 30 carbon atoms;
- and
- R4, R5 and R6 are each independently selected from the group consisting of a hydrogen atom, a halogen atom, a hydroxyl group, a substituted or unsubstituted alkyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having from 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having from 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having from 6 to 30 carbon atoms, a substituted or unsubstituted aryloxy group having from 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having from 2 to 30 carbon atoms, and a substituted or unsubstituted heteroaryloxy group having from 2 to 30 carbon atoms.
6 more elements
Dependencies are inferred from the claim text.