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US 7,678,232 B2Granted
Process for incorporating poorly substantive paper modifying agents into a paper sheet via wet end addition
AssigneeKimberly-Clark Worldwide, Inc.
InventorsThomas Gerard Shannon, Mike Thomas Goulet, Dana Stephanie Kass
Life of this patent
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Abstract
Synthetic co-polymers having moieties capable of forming hydrogen bonds, ionic bonds, or covalent bonds with cellulose fibers and paper modifying moieties capable of modifying a paper sheet are disclosed. These synthetic co-polymers are derived from the reaction of an aldehyde functional polymer and an aldehyde reactive paper modifying agent containing a non-hydroxyl aldehyde reactive functional group.
Claims23
A method of making a paper sheet comprising:
- (a) forming an aqueous suspension of papermaking fibers;
- (b) adding to the aqueous suspension, prior to web formation, a water soluble or water dispersible aldehyde functional ionic polymer followed by the addition of a paper modifying agent having a non-hydroxyl aldehyde reactive functional group, which react according to the following reaction:
- (c) filtering and washing the papermaking fibers containing the aldehyde functional ionic polymer reacted with derivatized paper modifying agent;
- (d) depositing the aqueous suspension of papermaking fibers onto a forming fabric to form a web;
- and (e) dewatering and drying the web to form a paper sheet,
- wherein:
- b, c, f>0;
- a, e≧0;
- e+f=b;
- w≧1;
- Q1=a monomer unit or a block or graft copolymer prepared from the polymerization of one or more ethylenically unsaturated compounds, said monomer unit or block or graft copolymer containing a pendant group capable of forming hydrogen bonds with cellulose;
- R1, R1′, R1″=independently H or C1-4 alkyl;
- R2=any linear or branched, aliphatic or aromatic, saturated or unsaturated, substituted or unsubstituted hydrocarbon group containing a pendant aldehyde functionality;
- R3=an aliphatic hydrocarbon, an amphiphilic hydrocarbon, humectant or other agent capable of modifying the paper sheet;
- Z1=a reactive group capable of reacting with an aldehyde in an aqueous environment to form a covalent bond which is stable in the aqueous environment;
- Z2=the covalently bonded bridging radical formed by the reaction of the aldehyde functionality with Z1 functional moiety;
- and
- Q3=a monomer unit or a block or graft copolymer, said monomer unit or block or graft copolymer containing a charge functionality wherein the charge functionality is selected from the group consisting of cationic, anionic and amphoteric.
15 more elements
Dependencies are inferred from the claim text.