Isoxazoline-substituted benzamide compound and pesticide

An isoxazoline-substituted benzamide compound of formula (1) or a salt thereof:

• wherein A1, A2 and A3 are carbon;
• G is a benzene ring;
• W is an oxygen atom or sulfur atom;
• X is halogen atom, cyano, nitro, azido, —SCN, —SF5, C1-C6alkyl, C1-C6alkyl arbitrarily substituted with R4, C3-C8cycloalkyl, C3-C8cycloalkyl arbitrarily substituted with R4, C2-C6alkenyl, C2-C6alkenyl arbitrarily substituted with R4, C3-C8cycloalkenyl, C3-C8halocycloalkenyl, C2-C6alkynyl, C2-C6alkynyl arbitrarily substituted with R4, —OH, —OR5, —OSO2R5, —SH, —S(O)rR5, —N═CHOR8, —N═C(R9)OR8, —CHO, —C(O)R9, —C(O)OR9, —C(O)SR9, —C(O)NHR10, —C(O)N(R10)R9, —C(S)OR9, —C(S)SR9, —C(S)NHR10, —C(S)N(R10)R9 —CH═NOR11, —C(R9)═NOR11, —S(O)2OR9, —S(O)2NHR10, —S(O)2N(R10)R9, —Si(R13)(R14)R12, phenyl, phenyl substituted with (Z)p1, D-1 to D-46, D-61 to D-65, E-1 to E-28, E32 to E-38 or E-43 to E-45, when m is 2, 3, 4 or 5, each X may be identical with or different from each other,
• further, when two Xs are adjacent, the adjacent two Xs may form 5-membered or 6-membered ring together with carbon atoms to which the two Xs are bonded by forming —CH2CH2CH2—, —CH2CH2O—, —CH2OCH2—, —OCH2O—, —CH2CH2S—, —CH2SCH2—, —CH2CH2N(R15)—, —CH2N(R15)CH2—, —CH2CH2CH2CH2—, —CH2CH2CH2O—, —CH2CH2OCH2—, —CH2OCH2O—, —OCH2CH2O—, —OCH2CH2S—, —CH2CH═CH—, —OCH═CH—, —SCH═CH—, —N(R15)CH═CH—, —OCH═N—, —SCH═N—, —N(R15)CH═N—, —N(R15)N═CH—, —CH═CHCH═CH— or —OCH2CH═CH—, in this case, hydrogen atoms bonded to each carbon atom forming the ring may be arbitrarily substituted with Z, further when the hydrogen atoms are substituted with two or more Zs at the same time, each Z may be identical with or different from each other;
• Y is halogen atom, cyano, nitro, azido, —SCN, —SF5, C1-C6alkyl, C1-C6alkyl arbitrarily substituted with R4, C3-C8cycloalkyl, C3-C8cycloalkyl arbitrarily substituted with R4, C2-C6alkynyl, C2-C6alkynyl arbitrarily substituted with R4, —OH, —OR5, —OSO2R5, —SH, —S(O)rR5, —NHR7, —N(R7)R6, —N═CHOR8, —N═C(R9)OR8, —C(O)NHR10, —C(O)N(R10)R9, —C(S)NHR10, —C(S)N(R10)R9, —Si(R13)(R14)R12, phenyl, phenyl substituted with (Z)p1, D-1 to D-46, D-61 to D-65, E-1 to E-28, E-32 to E-38 or E-43 to E-45, when n is 2, 3 or 4, each Y may be identical with or different from each other,
• further, when two Ys are adjacent, the adjacent two Ys may form 5-membered or 6-membered ring together with carbon atoms to which the two Ys are bonded by forming —CH2CH2CH2—, —CH2CH2O—, —CH2OCH2—, —OCH2O—, —CH2CH2S—, —CH2SCH2—, —SCH2S—, —CH2CH2CH2CH2—, —CH2CH2CH2O—, —CH2CH2OCH2—, —CH2OCH2O—, —OCH2CH2O—, —OCH2CH2S—, —SCH2CH2S—, —OCH═N— or —SCH═N—, in this case, hydrogen atoms bonded to each carbon atom forming the ring may be arbitrarily substituted with Z, further when the hydrogen atoms are substituted with two or more Zs at the same time, each Z may be identical with or different from each other;
• R1 and R2 independently of each other are hydrogen atom, cyano, C1-C12alkyl, C1-C12alkyl arbitrarily substituted with R16, C3-C12cycloalkyl, C3-C12cycloalkyl arbitrarily substituted with R16, C2-C12alkenyl, C2-C12alkenyl arbitrarily substituted with R16, C3-C12cycloalkenyl, C3-12halocycloalkenyl, C3-C12alkynyl, C3-C12alkynyl arbitrarily substituted with R16, —SR9, —S(O)2R9, —SN(R18)R17, —S(O)2N(R10)R9, —OR19, —N(R20)R19, —N═CHR19b, —N═C(R19b)R19a, —CHO, —C(O)R9, —C(O)OR9, —C(O)SR9, —C(O)N(R10)R9, —C(S)OR9, —C(S)SR9, —C(S)N(R10)R9, —C(═NR11)OR9, —C(═NR11)SR9, —C(═NR11)N(R10)R9, phenyl, phenyl substituted with (Z)p1, D-1 to D-46, D-61 to D-63, D-65, E-3 to E-9, E17, E-23 to E-28, E-33, E-34 or E-45,
• or R1 and R2 together form ═C(R2a)R1a, or R1 and R2 together may form 3- to 5-membered ring together with the nitrogen atom bonding them by forming C2-C4 alkylene chain, in this case, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and may be arbitrarily substituted with halogen atom, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy (C6)alkyl, C1-C6alkoxy, formyl, C1-C6alkylcarbonyl, C1-C6haloalkylcarbonyl, C1-C6alkoxycarbonyl, C1-C6haloalkoxycarbonyl, C1-C6alkylaminocarbonyl, C1-C6haloalkylaminocarbonyl, phenyl or phenyl substituted with (Z)p1, or in case where substituent Y is present at the adjacent position, R2 together with Y may form a 5-membered ring together with the atom bonding them by forming —CH2—, —CH2CH2—, —CH2O—, —CH2S—, —CH2N(R6)—, —CH═CH— or —CH═N—, in this case, hydrogen atoms bonded to each carbon atom forming the ring may be arbitrarily substituted with halogen atom, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylidene, C1-C6haloalkylidene, oxo or thioxo,
• R1a and R2a together may form a 5- or 6-membered ring together with the carbon atom bonding them by forming C4-C5 alkylene chain or C4-C5 alkenylene chain, in this case, the alkylene chain and the alkenylene chain may contain one to three oxygen atoms or sulfur atoms, or R1a and R2a together may form a 5-membered ring together with the carbon atom bonding them by forming C4 alkylene chain or C4 alkenylene chain, in this case, the alkylene chain and the alkenylene chain may contain one to three nitrogen atoms, and either ring may be arbitrarily substituted with halogen atom, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkylthio or C1-C6haloalkylthio;
• R3 is cyano, C1-C6alkyl arbitrarily substituted with R4, C3-C8cycloalkyl, C3-C8cycloalkyl arbitrarily substituted with R4, C3-C6alkenyl, C2-C6alkenyl arbitrarily substituted with R4, C3-C6alkynyl, C2-C6alkynyl arbitrarily substituted with R4, —OR5, —S(O)rR5, —N(R10)R9, —CHO, —C(O)R9, —C(O)OR9, —C(O)SR9, —C(O)NHR10, —C(O)N(R10)R9, —C(S)OR9, —C(S)SR9, —C(S)NHR10, —C(S)N(R10)R9, —CH═NOR11, —C(R9)═NOR11, —Si(R13)(R14)R12, —P(O)(OR21)2, phenyl, phenyl substituted with (Z)p1, D-1 to D-46, D-61 to D-65, E-1 to E-28, E-32 to E-38 or E-43 to E-45;
• D-1 to D-46, and D-61 to D-65 are aromatic heterocyclic rings of the following formulae, respectively
• Z is halogen atom, cyano, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C4alkoxy C1-C4alkyl, C1-C4haloalkoxy C1-C4alkyl, C1-C4alkylthio C1-C4alkyl, C1-C4haloalkylthio C1-C4alkyl, C1-C4alkylsulfinyl C1-C4alkyl, C1-C4haloalkylsulfinyl C1-C4alkyl, C1-C4alkylsulfonyl C1-C4alkyl, C1-C4haloalkylsulfonyl C1-C4alkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, —OH, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkylsulfonyloxy, C1-C6haloalkylsulfonyloxy, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkylsulfinyl, C1-C6haloalkylsulfinyl, C1-C6alkylsulfonyl, C1-C6haloalkylsulfonyl, —NH2, C1-C6alkylamino, di(C1-C6alkyl)amino, C1-C6alkoxycarbonyl, C1-C6haloalkoxycarbonyl, —C(O)NH2, C1-C6alkylaminocarbonyl, C1-C6haloalkylaminocarbonyl, di(C1-C6alkyl)aminocarbonyl, —C(S)NH2, —S(O)2NH2, C1-C6alkylaminosulfonyl, di(C1-C6alkyl)aminosulfonyl, phenyl or phenyl arbitrarily substituted with halogen atom, when p1, p2, p3 or p4 is an integer of 2 or more, each Z may be identical with or different from each other,
• further, when two Zs are adjacent, the adjacent two Zs may form 5-membered or 6-membered ring together with carbon atoms to which the two Zs are bonded by forming —CH2CH2CH2—, —CH2CH2O—, —CH2OCH2—, —OCH2O—, —CH2CH2S—, —CH2SCH2—, —CH2CH2CH2CH2—, —CH2CH2CH2O—, —CH2CH2OCH2—, —CH2OCH2O—, —OCH2CH2O—, —CH2CH2CH2S—, —OCH2CH2S— or —CH═CH—CH═CH—, in this case, hydrogen atoms bonded to each carbon atom forming the ring may be arbitrarily substituted with halogen atom, cyano, nitro, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy or C1-C4alkylthio;
• E-1 to E-28, E-32 to E-38 and E-43 to E-45 are saturated heterocyclic rings of the following formulae, respectively
• R4 is halogen atom, cyano, C3-C8cycloalkyl, C3-C8halocycloalkyl, —OH, —OR5, —SH, —S(O)rR5, —N(R10)R9, —N(R10)CHO, —N(R10)C(O)R9, —N(R10)C(O)OR9, —N(R10)C(O)SR9, —N(R10)C(S)OR9, —N(R10)C(S)SR9, —N(R10)S(O)2R9, —C(O)OR9, —C(O)N(R10)R9, —Si(R13)(R14)R12, phenyl, phenyl substituted with (Z)p1 D-1 to D-46, D-61 to D-65, E-1 to E-28, E-32 to E-38 or E-43 to E-45;
• R5 is C1-C6alkyl, C1-C6alkyl arbitrarily substituted with R24, C3-C8cycloalkyl, C3-C8cycloalkyl arbitrarily substituted with R24, C2-C6alkenyl, C2-C6alkenyl arbitrarily substituted with R24, C3-C8cycloalkenyl, C3-C8halocycloalkenyl, C3-C6alkynyl, C3-C6alkynyl arbitrarily substituted with R24, C1-C6alkylcarbonyl, C1-C6alkoxycarbonyl, phenyl, phenyl substituted with (Z)p1, D-1 to D-4, D-6 to D-13, D-15 to D-23, D-25 to D-37, D-39, D-40, D-42, D-45 to D-46, D-62, D-63, D-65, E-3 to E-9, E-23 to E-28, E-34 or E-45;
• R6 is C1-C6alkyl, C1-C6alkyl arbitrarily substituted with R24, C3-C6cycloalkyl, C3-C8halocycloalkyl, C3-C6alkenyl, C3-C6haloalkenyl, C3-C6alkynyl, C3-C6haloalkynyl, —OH, C1-C6alkylcarbonyloxy, C1-C6alkylthio, C1-C6haloalkylthio, phenylthio, phenylthio substituted with (Z)p1, —SN(R18)R17, —S(O)2R9, —S(O)2N(R10)R9, —CHO, —C(O)R9, —C(O)OR9, —C(O)SR9, —C(O)NHR10, —C(O)N(R10)R9, —C(S)OR9, —C(S)SR9, —C(S)NHR10, —C(S)N(R10)R9, —C(O)C(O)R9, —C(O)C(O)OR9, —P(O)(OR21)2 or —P(S)(OR21)2;
• R7 is hydrogen atom, C1-C6alkyl, C1-C6haloalkyl, C3-C8cycloalkyl C1-C6alkyl, C1-C4alkoxy C1-C4alkyl, C1-C4 alkylthio C1-C4alkyl, C3-C8cycloalkyl, C3-C6alkenyl, C3C6haloalkenyl, C3-C6alkynyl, C3-C6haloalkynyl, —CHO, C1-C6alkylcarbonyl, C1-C6haloalkylcarbonyl or C1-C6alkoxycarbonyl, or R7 together with R6 may form 3- to 5-membered ring with the bonding nitrogen atom by forming C2-C4 alkylene chain, in this case, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and may be arbitrarily substituted with halogen atom, C1-C6alkyl, C1-C6haloalkyl, oxo or thioxo;
• R8 is C1-C6alkyl, C1-C6haloalkyl, C3-C6alkenyl, phenyl or phenyl substituted with (Z)p1;
• R9 is C1-C6alkyl, C1-C6alkyl arbitrarily substituted with R24, C3-C8cycloalkyl, C3-C8halocycloalkyl, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C2-C6haloalkynyl, phenyl, phenyl substituted with (Z)p1 D-1 to D-46, D-61 to D-65, E-1 to E-28, E-32 to E-38 or E-43 to E-45;
• R10 is hydrogen atom, C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl C1-C4alkyl, C1-C6alkoxy C1-C4alkyl, C1-C6alkylthio C1-C4alkyl, cyano C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl, R10 together with R9 may form a 3- to 7-membered ring with the atom bonding them by forming a C2-C6alkylene chain, in this case, the alkylene chain may contain one oxygen atom or sulfur atom, or R10 together with R9 may form a 3- to 5-membered ring with the atom bonding them by forming a C2-C4alkylene chain, in this case, the alkylene chain may contain one nitrogen atom, and either ring may be arbitrarily substituted with halogen atom, C1-C6alkyl or C1-C6haloalkoxy, formyl, C1-C6alkylcarbonyl or C1-C6alkoxycarbonyl;
• R11 is hydrogen atom, C1-C6alkyl, C1-C6haloalkyl, phenyl C1-C4alkyl, phenyl C1-C4alkyl substituted with (Z)p1, C3-C6alkenyl, C3-C6haloalkenyl, C3-C6alkynyl, C3-C6haloalkynyl, phenyl or phenyl that may be substituted with (Z)p1, R11 together with R9 may form 5- to 7-membered ring with the atom bonding them by forming C2-C4alkylene chain, in this case, the alkylene chain may contain one oxygen atom or sulfur atom, or R11 together with R9 may form a 5-membered ring with the atom bonding them by forming C2-alkylene chain, in this case, the alkylene chain may contain one nitrogen, and either ring may be arbitrarily substituted with halogen atom, C1-C6alkyl or C1-C6haloalkyl;
• R12 is C1-C6alkyl, C1-C6haloalkyl, phenyl or phenyl substituted with (Z)p1;
• R13 and R14 independently of each other are C1-C6alkyl or C1-C6haloalkyl;
• R15 is hydrogen atom, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxycarbonyl C1-C4alkyl, C1-C6haloalkoxycarbonyl C1-C4alkyl, phenyl C1-C4alkyl, phenyl C1-C4alkyl substituted with (Z)p1, C3-C6alkenyl, C3-C6haloalkenyl, C3-C6alkynyl, C3-C6haloalkynyl, C1-C6alkoxy, C1-C6alkoxycarbonyl, C1-C6haloalkoxycarbonyl, phenyl or phenyl substituted with (Z)p1, further, in case where Z is present in an adjacent position of R15, the adjacent R15 and Z may form 6-membered ring together with the atom bonding them by forming —CH2CH2CH2CH2— or —CH═CH—CH═CH—, in this case, hydrogen atoms bonded to each carbon atom forming the ring may be arbitrarily substituted with halogen atom, C1-C4alkyl or C1-C4haloalkyl;
• R16 is halogen atom, cyano, nitro, C3-C8cycloalkyl, C3-C8halocycloalkyl, hydroxy C3-C6cycloalkyl, C1-C4alkoxy C3-C6cycloalkyl, C5-C6cycloalkenyl, —O25, —N(R26)R25, —SH, —S(O)rR27, —SO2OH, —SO2NHR29, —SO2N(R29)R28, —CHO, —C(O)R28, —C(O)OH, —C(O)OR28, —C(O)SR28, —C(O)NHR29, —C(O)N(R29)R28, —C(O)N(R29)OR28, —C(O)N(R29)N(R28a)R28, —C(S)OR28, —C(S)SR28, —C(S)NHR29, —C(S)N(R29)R28, —C(O)C(O)OR28, —C(R31)═NOH, —C(R31)═NOR30, —C(═NR31)OR30, —C(═NR31)SR30, —C(═NR31)N(R29)R30, —C(═NOR31)NHR29, —C(═NOR31)N(R29)R30, —Si(R13)(R14)R12, —P(O)(OR21)2, —P(S)(OR21)2, —P(phenyl)2, —P(O)(phenyl)2, phenyl, phenyl substituted with (Z)p1, naphthyl D-1 to D-46, D-61 to D-65, E-1 to E-28, E-32 to E-38, E-43 to E-45 or M-1 to M-11;
• M-1 to M-11 are partially saturated heterocyclic rings of the following formulae, respectively
• R17 is C1-12alkyl, C1-C12haloalkyl, C1-12alkoxy C1-12alkyl, cyano C1-12alkyl, C1-12alkoxycarbonyl C1-12alkyl, phenyl C1-C4alkyl, phenyl C1-C4alkyl substituted with (Z)p1, C3-C12alkenyl, C3-C12haloalkenyl, C3-C12alkynyl, C3-C12haloalkynyl, C1-C12alkylcarbonyl, C1-C12alkoxycarbonyl, —C(O)ON═C(CH3)SCH3, —C(O)ON═C(SCH3)C(O)N(CH3)2, phenyl or phenyl substituted with (Z)p1;
• R18 is C1-C12alkyl, C1-C12haloalkyl, C1-12alkoxy C1-12alkyl, cyano C1-12alkyl, C1-C12alkoxycarbonyl C1-12alkyl, phenyl C1-C4alkyl, phenyl C1-C4alkyl substituted with (Z)p1, C3-C12alkenyl, C3-12haloalkenyl, C3-C12alkynyl, C3-C12haloalkynyl, phenyl or phenyl substituted with (Z)p1, or R18 together with R17 may form a 5-membered ring with the nitrogen atom bonding them by forming C4alkylene chain, in this case, the alkylene chain may contain one oxygen atom or sulfur atom, and may be arbitrarily substituted with C1-C4alkyl or C1-C4alkoxy;
• R19 is hydrogen atom, C1-C6alkyl, C1-C6alkyl arbitrarily substituted with R16, C3-C8cycloalkyl, C3-C8halocycloalkyl, C3-C6alkenyl, C3-C6haloalkenyl, C3-C6alkynyl, C3-C6haloalkynyl, —CHO, —C(O)R28, —C(O)OR28, —C(O)SR28, —C(O)NHR29, —C(O)N(R29)R28, —C(S)OR28, —C(S)SR28, —C(S)NHR29, —C(S)N(R29)R28, —S(O)2R28, —S(O)2NHR29, —S(O)2N(R29)R28, —P(O)(OR21)2, —P(S)(OR21)2, phenyl, phenyl substituted with (Z)p1, D-1 to D-13, D-15 to D-25, D-30 to D-37, D-39, D-40, D-42, D-45 to D-46, E-5, E-7, E-9, E-24, E-25, E-27 or E-28;
• R19a is hydrogen atom, C1-C6alkyl, C1-C6haloalkyl, C1-C4alkoxy C1-C4alkyl, C1-C4alkylthio C1-C4alkyl, C1-C4alkylsulfonyl C1-C4alkyl, C1-C4alkoxycarbonyl C1-C4alkyl, phenyl C1-C4alkyl, phenyl C1-C4alkyl substituted with (Z)p1, C3-C6cycloalkyl, phenyl C2-C4alkenyl, di(C1-C6alkyl)amino, phenyl, or phenyl substituted with (Z)p1 D-1 to D-46, D-61 to D-65, E-1 to E-28, E-32 to E-38 or E-43 to E-45;
• R19b is hydrogen atom, C1-C6alkyl, C1-C6alkoxy, C1-C6alkylthio or di(C1-C6alkyl)amino, or R19a together with R19b may form R19b may form 4- to 6-membered ring with the carbon atom bonding them by forming C3-C5alkylene chain, in this case, the alkylene chain may contain one oxygen atom or sulfur atom, or R19a together with R19b may form 4- to 5-membered ring with the carbon atom bonding them by forming C3-C4alkylene chain, in this case, the alkylene chain may contain one nitrogen, and either ring may be arbitrarily substituted with halogen atom, C1-C6alkyl, C1-C6haloalkyl, formyl, C1-C6alkylcarbonyl or C1-C6alkoxycarbonyl;
• R20 is hydrogen atom, C1-C6alkyl, C1-C6haloalkyl, C1-C4alkoxy C1-C4alkyl, C1-C4haloalkoxy C1-C4alkyl, C1-C4alkylthio C1-C4alkyl, C1-C4haloalkylthio C1-C4alkyl, C1-C4alkylsulfonyl C1-C4alkyl, C1-C4haloalkylsulfonyl C1-C4alkyl, cyano C1-C6alkyl, C1-C4alkoxycarbonyl C1-C4alkyl, phenyl C1-C4alkyl, C2-C6alkenyl, C2-C6haloalkenyl, C3-C6alkynyl, C3-C6haloalkynyl, —CHO, —C(O)R9, —C(O)OR9, —C(O)SR9, —C(S)OR9, —C(S)SR9, C1-C6alkylsulfonyl or C1-C6haloalkylsulfonyl, or R20 together with R19 may form a 5-membered ring with the nitrogen atom bonding them by forming C4alkylene chain, in this case, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and may be arbitrarily substituted with C1-C6alkyl, C1-C6alkoxy C1-C6alkyl, —CHO, C1-C6alkylcarbonyl or C1-C6alkoxycarbonyl;
• R21 is C1-C6alkyl or C1-C6haloalkyl;
• R22 is halogen atom, cyano, C1-C6alkyl, C1-C6haloalkyl, hydroxy C1-C6alkyl, C1-C4alkoxy C1-C4alkyl, C1-C4alkoxycarbonyl C1-C4alkyl, C1-C6alkoxy, C1-C6alkylthio, C1-C6alkylamino, di(C1-C4alkyl)amino, C1-C6alkoxycarbonyl, phenyl or phenyl substituted with (Z)p1, when q1, q2, q3 or q4 is an integer of 2 or more, each R22 may be identical with or different from each other, further in case where two R22s are present on the same carbon atom, the two R22s together may form oxo, thioxo, imino, C1-C6alkylimino, C1-C6alkoxyimino or C1-C6alkylidene;
• R23 is hydrogen atom, C1-C6alkyl, C1-C6alkyl substituted with R32, C3-C6cycloalkyl, C3-C6alkenyl, C3-C6haloalkenyl, C3-C6alkynyl, —OH, benzyloxy, —CHO, —C(O)R33, —C(O)OR33, —C(O)SR33, —C(O)NHR34, —C(O)N(R34)R33, —C(S)NHR34, —C(S)N(R34)R33, —S(O)2R33, —P(O)(OR21)2, —P(S)(OR21)2, phenyl, phenyl substituted with (Z)p1 or D-5;
• R24 is halogen atom, cyano, C3-C8cycloalkyl, C3-C8halocycloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkylsulfonyl, C1-C6haloalkylsulfonyl, C1-C6alkylamino, di(C1-C6alkyl)amino, —CHO, C1-C6alkylcarbonyl, C1-C6haloalkylcarbonyl, C1-C6alkoxycarbonyl, C1-C6haloalkoxycarbonyl, C1-C6alkylaminocarbonyl, di(C1-C6alkyl)aminocarbonyl, phenyl or phenyl substituted with (Z)p1 D-1 to D-46, D-61 to D-65, E-1 to E-28, E-32 to E-38 or E-43 to E-45;
• R25 is hydrogen atom, C1-C8alkyl, C1-C8alkyl arbitrarily substituted with R32, C3-C8cycloalkyl, C3-C8cycloalkyl arbitrarily substituted with R32, C3-C8alkenyl, C3-C8alkenyl arbitrarily substituted with R32, C3-C8alkynyl, C3-C8alkynyl arbitrarily substituted with R32, —CHO, —C(O)R33, —C(O)OR33, —C(O)SR33, —C(O)NHR34, C(O)N(R34)R33, —C(O)C(O)R33, —C(O)C(O)OR33, —C(S)R33, —C(S)OR33, —C(S)SR33, —C(S)NHR34, —C(S)N(R34)R33, —S(O)2R33, —S(O)2N(R34)R33, —Si(R13)(R14)R12, —P(O)(OR21)2, —P(S)(OR21)2, phenyl, phenyl substituted with (Z)p1, D-1 to D-4, D-6 to D-13, D-15 to D-23, D-25 to D-37, D-39, D-40, D-42, D-45 to D-46, D-62, D-63, D-65, E-3 to E-9, E-23 to E-28, E-34 or E-45 ;
• R26 is hydrogen atom, C1-C6alkyl, C1-C6haloalkyl, C1-C4alkoxy C1-C4alkyl, C1-C4alkylthio C1-C4alkyl, C3-C6cycloalkyl, C3-C6alkenyl, C3-C6alkynyl, C1-C6alkoxy, phenyl or phenyl substituted with (Z)p1, or R26 together with R25 may form 3- to 5-membered ring with the nitrogen atom bonding them by forming C2-C4 alkylene chain, in this case, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and may be substituted with halogen atom, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, phenyl, phenyl substituted with (Z)p1, oxo or thioxo;
• R27 is C1-C8alkyl, C1-C8alkyl arbitrarily substituted with R32, C3-C8cycloalkyl, C3-8cycloalkyl arbitrarily substituted with R32, C3-C8alkenyl, C3-C8alkenyl arbitrarily substituted with R32, C3-C8alkynyl, C3-C8alkynyl arbitrarily substituted with R32, —SH, C1-C6alkylthio, C1-C6haloalkylthio, phenylthio, phenylthio substituted with (Z)p1, —CHO, —C(O)R33, —C(O)OR33, —C(O)SR33, —C(O)NHR34, —C(O)N(R34)R33, —C(O)C(O)R33, —C(O)C(O)OR33, —C(S)R33, —C(S)OR33, —C(S)SR33, —C(S)NHR34, —C(S)N(R34)R33, —P(O)(OR21)2, —P(S)(OR21)2, phenyl, phenyl substituted with (Z)p1, D-18, D-21, D-25, D-30 to D-35, E-3 to E-9, E-23 to E-28, E-34 or E-45;
• R28 is C1-C6alkyl, C1-C6alkyl arbitrarily substituted with R32, C3-C8cycloalkyl, C3-C8cycloalkyl arbitrarily substituted with R32, C2-C6alkenyl C3-C8cycloalkyl, C2-C6haloalkenyl C3-C8cycloalkyl, C2-C8alkenyl, C2-C8alkenyl arbitrarily substituted with R32, C2-C8alkynyl, C2-C8alkynyl arbitrarily substituted with R32, phenyl or phenyl substituted with (Z)p1 D-1 to D-46, D-61 to D-65, E-1 to E-28, E-32 to E-38 or E-43 to E-45;
• R28a is hydrogen atom or C1-C6alkyl;
• R29 is hydrogen atom, C1-C6alkyl, C1-C6alkyl arbitrarily substituted with R32, C3-C6alkenyl, C3-C6haloalkenyl, C3-C6alkynyl, C3-C6haloalkynyl, phenyl or phenyl substituted with (Z)p1, or R29 together with R28 may form 3- to 5-membered ring with the nitrogen atom bonding them by forming C2-C4 alkylene chain, in this case, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and may be arbitrarily substituted with halogen atom, C1-C6alkyl, C1-C6alkoxy, formyl, C1-C6alkylcarbonyl, C1-C6alkoxycarbonyl, phenyl or phenyl substituted with (Z)p1;
• R30 is C1-C8alkyl, C1-C8alkyl arbitrarily substituted with R32, C3-C8cycloalkyl, C3-C8alkenyl, C3-C8alkenyl arbitrarily substituted with R32, C3-C8alkynyl, C3-C8alkynyl arbitrarily substituted with R32;
• R31 is hydrogen atom, C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl C1-C4alkyl, C1-C6alkoxy C1-C4alkyl, C1-C6haloalkoxy C1-C4alkyl, C1-C6alkylthio C1-C4alkyl, C1-C6haloalkylthio C1-C4alkyl, C1-C6alkylsulfonyl C1-C4alkyl, C1-C6haloalkylsulfonyl C1-C4alkyl, phenyl C1-C4alkyl, phenyl C1-C4alkyl substituted with (Z)p1, C3-C6cycloalkyl, phenyl or phenyl substituted with (Z)p1, or R31 together with R30 may form 5- to 7-membered ring with the atom bonding them by forming C2-C4alkylene chain, in this case, the alkylene chain may contain one oxygen atom or sulfur atom, or R31 together with R30 may form a 5-membered ring with the atom bonding them by forming C2alkylene chain, in this case, the alkylene chain may contain one nitrogen, and either ring may be arbitrarily substituted with halogen atom, C1-C6alkyl or C1-C6haloalkyl;
• R32 is halogen atom, cyano, nitro, C3-C8cycloalkyl, C3-C8halocycloalkyl, —OH, —OR33, —OC(O)R33, —OC(O)OR33, —OC(O)NHR34, —OC(O)N(R34)R33, —OC(S)NHR34, —OC(S)N(R34)R33, —SH, —S(O)rR33, —SC(O)R33, —SC(O)OR33, —SC(O)NHR34, —SC(O)N(R34)R33, —SC(S)NHR34, —SC(S)N(R34)R33, —NHR34, —N(R34)R33, —N(R34)CHO, —N(R34)C(O)R33, —N(R34)C(O)OR33, —N(R34)C(O)NHR34, —N(R34)C(O)N(R34)R33, —N(R34)C(S)NHR34, —N(R34)C(S)N(R34)R33, —CHO, —C(O)R33, —C(O)OR33, —C(O)SR33, —C(O)NHR34, —C(O)N(R34)R33, —C(O)C(O)OR33, —Si(R13)(R14)R12, —P(O)(OR21)2, —P(S)(OR21)2, —P(phenyl)2, —P(O)(phenyl)2, phenyl, phenyl substituted with (Z)p1, D-1 to D-46, D-61 to D-65 or E-4 to E-7, E-10 to E-14, E-18, E-19, E-23 to E-28, E-32 to E-38, E-43, E-44 or E-45;
• R33 is C1-C6alkyl, C1-C6haloalkyl, C1-C4alkyl arbitrarily substituted with R35, C3-C6cycloalkyl, C3-C6halocycloalkyl, C2-C6alkenyl C3-C8cycloalkyl, C2-C6haloalkenyl C3-C8cycloalkyl, C2-C8alkenyl, C2-C8haloalkenyl, C3-C8cycloalkenyl, C3-C8halocycloalkenyl, C2-C8alkynyl, C2-C8haloalkynyl, phenyl or phenyl substituted with (Z)p1, D-1 to D-46, D-61 to D-65, E-4 to E-7, E-23 to E-27 or E-28;
• R34 is hydrogen atom, C1-C6alkyl, C1-C6haloalkyl, C3-C8cycloalkyl, C3-C6alkenyl, C3-C6alkynyl, C1-C6alkylcarbonyl, C1-C6haloalkylcarbonyl, C1-C6alkoxycarbonyl, C1-C6haloalkoxycarbonyl, phenoxycarbonyl, phenoxycarbonyl substituted with (Z)p1, phenylcarbonyl, phenylcarbonyl substituted with (Z)p1, C1-C6alkylsulfonyl, C1-C6haloalkylsulfonyl, phenyl, phenyl substituted with (Z)p1, D-1 to D-4, D-6 to D-13, D-15 to D-23, D-25 to D-37, D-39, D-40, D-42, D-45 to D-46, D-62, D-63 or D-65, or R34 together with R33 may form 3- to 5-membered ring with the nitrogen atom bonding them by forming C2-C5alkylene chain, in this case, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and may be arbitrarily substituted with halogen atom, C1-C6alkyl, C1-C6alkoxy, formyl, C1-C6alkylcarbonyl, C1-C6alkoxycarbonyl, phenyl or phenyl substituted with (Z)p1;
• R35 is cyano, C3-C6cycloalkyl, C3-C6halocylcoalkyl, E-4 to E-7, E-23 to E-28, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylthio, C1-C4haloalkylthio, C1-C4alkylsulfonyl, C1-C4haloalkylsulfonyl, C1-C6alkylcarbonyl, C1-C6haloalkylcarbonyl, C1-C6alkoxycarbonyl, di(C1-C6alkyl)aminocarbonyl, tri(C1-C6alkyl)silyl, phenyl, phenyl substituted with (Z)p1, D-1 to D-46 or D-61 to D-65;
• m is an integer of 0 to 5;
• n is an integer of 0 to 4;
• p1 is an integer of 1 to 5;
• p2 is an integer of 0 to 4;
• p3 is an integer of 0 to 3;
• p4 is an integer of 0 to 2;
• p5 is an integer of 0 or 1;
• q1 is an integer of 0 to 3;
• q2 is an integer of 0 to 5;
• q3 is an integer of 0 to 7;
• q4 is an integer of 0 to 9;
• r is an integer of 0 to 2;
• and
• t is an integer of 0 or 1.