Polysiloxane and textile auxiliary containing a polysiloxane
AssigneeCHT R. Beitlich GmbH
InventorsPeter Will, Matthias Koch, Friedhelm Nickel
Life of this patent
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Abstract
The present invention relates to a polysiloxane of the general formula (I) having at least one epoxidic radical and at least one quaternary nitrogen atom and also a textile auxiliary which comprises at least one polysiloxane according to the present invention. The polysiloxane is capable of crosslinking with or on the fiber.
Claims16
A polysiloxane of the general formula (I)
- where m is an integer from 5-200,
- n is an integer from 0-25,
- k is an integer from 1-25,
- R1 is an aliphatic C1 to C30 radical or a phenyl radical,
- R2 is an aliphatic C9 to C30 radical and/or a polyether radical of the general formula (CH2)3O(C2H4O)x(C3H6O)yQ, where x and y may be the same or different and are each an integer between 0 and 50 and Q is hydrogen or an alkyl radical of 1 to 4 carbon atoms,
- R3 is an epoxidic radical,
- E is an MZ radical, R3 or R2,
- each molecule containing at least one epoxidic radical and one MZ radical,
- the epoxidic radical being selected from the group consisting of
- M being selected from the group consisting of
- Z being selected from the group consisting of
- where the quaternary nitrogen atom of the Z radical is attached to the M radical via the carbon atom adjacent to the C—OH group in the M radical,
- R4, R5 and R6 may be the same or different and may denote H, C1 to C22 alkyl, C1 to C22 alkenyl, which alkyl or alkylene radicals may contain hydroxyl groups,
- R8 and R9 may be the same or different and each has the same meaning as R4, R5 and R6 or are fluorine-, chlorine- or bromine-substituted C1 to C10 alkyl radicals,
- R10 is an —O— or an NR11 radical where R11═H, C1 to C4 alkyl or C1 to C4 hydroxyalkyl,
- o is an integer from 1 to 4,
- A⊖ is an organic or inorganic anion derived from a customary physiologically tolerable acid HX, where the epoxidic radical is selected from ether epoxies, where the M component of the MZ radical is selected from primary/secondary straight chain alcohols, and where the Z component of the MZ radical is selected from guaternary ammoniums.
A polysiloxane according to either of the preceding claims, characterized in that R2 is an aliphatic C10 to C20 radical.
A textile auxiliary, characterized in that it contains 2% to 80% by weight of at least one polysiloxane according to claim 1, 0% to 40% by weight of at least one emulsifier, 0% to 5% by weight of at least one inorganic and/or organic acid and/or of an acid anhydride, 0% to 40% by weight of at least one customary finishing agent, 0% to 20% by weight of at least one hydrotrope, and also 0% to 98% by weight of water.
Dependencies are inferred from the claim text.