Sidewall functionalization of nanotubes with hydroxyl terminated moieties
AssigneeWilliam Marsh Rice University
InventorsValery N. Khabashesku, Lei Zhang, John L. Margrave
Life of this patent
Estimating the term…
Loading patent…
AssigneeWilliam Marsh Rice University
InventorsValery N. Khabashesku, Lei Zhang, John L. Margrave
Estimating the term…
The present invention is directed to methods of forming sidewall-functionalized carbon nanotubes, wherein such functionalized carbon nanotubes have hydroxyl-terminated moieties covalently attached to their sidewalls. Generally, such methods involve chemistry on carbon nanotubes that have first been fluorinated. In some embodiments, fluorinated carbon nanotubes (“fluoronanotubes”) are reacted with mono-metal salts of a dialcohol, MO—R—OH, where M is a metal and R is hydrocarbon or other organic chain and/or ring structural unit. In such embodiments, —O—R—OH displaces —F on the nanotube, the fluorine leaving as MF. Generally, such mono-metal salts are formed in situ by the addition of MOH to one or more dialcohols in which the fluoronanotubes have been dispersed. In some embodiments, fluoronanotubes are reacted with amino alcohols, such as being of the type H2N—R—OH, wherein —N(H)—R—OH displaces —F on the nanotube, the fluorine leaving as HF.
A method comprising the steps of:
A method comprising the steps of:
Functionalized carbon nanotubes made by a process comprising the steps of:
Functionalized carbon nanotubes comprising:
Functionalized carbon nanotubes comprising a plurality of carbon nanotubes having functional groups comprising epoxide moieties attached to the sidewalls of the carbon nanotubes, wherein:
Dependencies are inferred from the claim text.