Polymerization catalyst composition for ethylene oxide and proces for the production of poly(ethylene oxide) with the same
AssigneeMeisei Chemical Works, Ltd.
InventorHideki Izumi
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AssigneeMeisei Chemical Works, Ltd.
InventorHideki Izumi
Estimating the term…
Provided are a polymerization catalyst composition for ethylene oxide which can give polyethylene oxide having a molecular weight lower than that of the prior art and a relatively narrow molecular weight distribution, and a process for the production of polyethylene oxide by the use of the catalyst composition. The catalyst composition makes it possible to produce polyethylene oxide having a molecular weight ranging from about 20,000 to 200,000 through direct polymerization in a high yield with economic advantage, and is characterized by comprising an organoaluminum compound and at least one member selected from among alkali metal alkoxides and alkali metal hydroxides. According to the process, polyethylene oxide having a molecular weight failing within the above range can be produced by the use of the catalyst composition under the same polymerication conditions as those of the prior art.
A catalyst composition for producing a polyethylene oxide polymer having a molecular weight range from 20,000 to 200,000 by direct polymerization economically in a high yield, wherein the catalyst composition consists of both component A and component B, said component A being an organoaluminum compound selected from the group consisting of a trialkylaluminum compound and a tricycloalkylaluminum compound, and said component B being at least one kind of an alkali metal alkoxide compound.
Dependencies are inferred from the claim text.