Catalyst composition for use in a lean NOx trap and method of using
AssigneeFord Global Technologies, LLC
InventorsJohn Li, Christian Goralski, Jr., William Watkins, George Graham, Harendra Gandhi
Life of this patent
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Abstract
A lean NOx trap composition. The lean NOx trap composition utilizes ruthenium in place of higher cost metals such as platinum. The lean NOx trap composition provides high NOx storage efficiency and high NOx conversion efficiency when incorporated in a lean NOx trap. A method of removing harmful gases using the lean NOx trap composition is also described.
Claims20
A lean NOx trap composition comprising:
- a support material;
- a ruthenium catalyst wherein the ruthenium catalyst is free of other precious metals;
- and
- a NOx absorbent material comprising an alkaline earth metal;
- wherein the lean NOx trap composition has a storage efficiency of at least 70% at a temperature in a range of from about 400° C. to about 500° C., and a conversion efficiency of at least 50% at a temperature in a range of from about 300° C. to about 450° C.
A lean NOx trap composition comprising:
- a support material;
- about 0.1 to about 10% by weight of washcoat of a ruthenium catalyst wherein the ruthenium catalyst is free of other precious metals;
- and
- about 5 to about 50% by weight of a NOx absorbent material comprising an alkaline earth metal;
- wherein the lean NOx trap composition has a storage efficiency of at least 70% at a temperature in a range of from about 400° C. to about 500° C., and a conversion efficiency of at least 50% at a temperature in a range of from about 300° C. to about 450° C.
A method of removing harmful gases from an automobile exhaust containing NOx, CO, and hydrocarbons, the method comprising:
- contacting a lean NOx trap composition with a first exhaust gas mixture, the first exhaust gas mixture comprising exhaust gases from an internal combustion engine operating in a fuel-lean condition, the lean NOx trap composition comprising:
- a support material;
- a ruthenium catalyst wherein the ruthenium catalyst is free of other precious metals;
- and
- a NOx absorbent material comprising an alkaline earth metal;
- wherein the lean NOx trap composition has a storage efficiency of at least 70% at a temperature in a range of from about 400° C. to about 500° C., and a conversion efficiency of at least 50% at a temperature in a range of from about 300° C. to about 450° C.;
- and
- contacting the lean NOx trap composition with a second exhaust mixture, the second exhaust gas mixture comprising exhaust gases from the internal combustion engine operating in a fuel-rich condition.
Dependencies are inferred from the claim text.