# US 7,611,776 B2 · Propylene polymer composition and oriented film prepared thereby > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 7,611,776 B2 - Document ID: US7611776B2 - Status: Granted - Kind: B2 - Application number: 11/338,619 - Filed: 2006-01-24 - Published: 2006-08-17 - Granted: 2009-11-03 - Earliest claimed: 2005-01-28 - Assignees: China Petrochemical & Chemical Corporation; Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation - Inventors: Luqiang Yu; Meifang Guo; Shijun Zhang; Jinliang Qiao; Wenbo Song; Qingshan Ma; Wei Zhang; Liangshi Wang; Xi Wang; Hao Tang; Rongmei Liu - Web page: https://patentgrep.com/patent/US7611776B2 ## CPC - C08F 210/06: Propene - C08F 10/00: Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond - C08L 23/12: Polypropene - C08F 110/06: Propene - C08L 23/142: {at least partially crystalline copolymers of propene with other olefins} - Y10T 428/31855: Of addition polymer from unsaturated monomers - Y10T 428/31909: Next to second addition polymer from unsaturated monomers - Y10T 428/31913: Monoolefin polymer - Y10T 428/31938: Polymer of monoethylenically unsaturated hydrocarbon - C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS - C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06) - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract The present invention provides a propylene polymer composition for producing a biaxially oriented film, comprising propylene random copolymer and propylene homopolymer; wherein the propylene random copolymer is a copolymer of propylene and ethylene, optionally comprising one or more alpha-olefins of C4-C10; the propylene polymer composition has an overall isotacticity index, as determined by nuclear magnetic resonance method, of greater than or equal to 96.5%, and an ethylene content of greater than 0.3 wt %; and wherein, the melt flow rate of the propylene random copolymer is lower than that of the propylene homopolymer. The biaxially oriented polypropylene film produced by the propylene polymer composition of the present invention exhibits excellent physical properties, and has, in the absence of any stiffening agent, relatively higher modulus and stiffness. Moreover, the process for producing the biaxially oriented polypropylene film is featured with a good film-forming stability and a high film-forming stretching speed. ## Claims ### Claim 1 A propylene polymer composition comprising propylene random copolymer and propylene homopolymer; wherein the propylene random copolymer is a copolymer of propylene and ethylene, optionally comprising one or more alpha-olefins of C4-C10; the propylene polymer composition has an overall isotacticity index, as determined by nuclear magnetic resonance method, of greater than or equal to 96.5%, and an ethylene content of 0.3 wt % to 0.8 wt %. ### Claim 2 (depends on 1) The propylene polymer composition according to claim 1, wherein the melt flow rate of the propylene random copolymer is lower than that of the propylene homopolymer. ### Claim 3 (depends on 1) The propylene polymer composition according to claim 1, which has an overall isotacticity index of greater than or equal to 97%. ### Claim 4 (depends on 1) The propylene polymer composition according to claim 1, which has an overall isotacticity index of greater than or equal to 97.5%. ### Claim 5 (depends on 1) The propylene polymer composition according to claim 1, which has a Dispersion index R of less than or equal to 2.5 according to the crystallization distribution curve as determined by a CRYSTAF model 200. ### Claim 6 (depends on 1) The propylene polymer composition according to claim 1, which has a Dispersion index R of less than or equal to 2.0 according to the crystallization distribution curve as determined by a CRYSTAF model 200. ### Claim 7 (depends on 1) The propylene polymer composition according to claim 1, wherein the content of fraction soluble in xylene at room temperature 25° C. is less than 3.0 wt %. ### Claim 8 (depends on 1) The propylene polymer composition according to claim 1, wherein the propylene random copolymer has a melt flow rate of 0.05-0.5 g/10 min, and the propylene polymer composition has a melt flow rate of 1-8 g/10 min, as determined under a load of 2.16 kg at 230° C. according to the method of ISO1133. ### Claim 9 (depends on 1) The propylene polymer composition according to claim 1, wherein the propylene random copolymer has a melt flow rate of 0.1-0.3 g/10 min, and the propylene polymer composition has a melt flow rate of 1-3 g/10 min. ### Claim 10 (depends on 1) The propylene polymer composition according to claim 1, which has a molecular weight distribution index Mw/Mn of 4-10. ### Claim 11 (depends on 1) The propylene polymer composition according to claim 1, wherein the mass ratio of the propylene random copolymer and the propylene homopolymer is 30:70-70:30. ### Claim 12 (depends on 1) The propylene polymer composition according to claim 1, comprising propylene random copolymer and propylene homopolymer, wherein the propylene random copolymer is a copolymer of propylene and ethylene, and the propylene polymer composition is characterized by having: (1) an overall isotacticity index, as determined by nuclear magnetic resonance method, of greater than or equal to 97%; (2) an ethylene content of 0.3-0.8 wt %; and (3) a Dispersion index R of less than or equal to 2.5 according to the crystallization distribution curve as determined by a CRYSTAF model 200. ### Claim 13 (depends on 12) The propylene polymer composition according to claim 12, wherein the content of fraction soluble in xylene at room temperature 25° C. is less than 2.6 wt %, and the propylene polymer composition has a melt flow rate of 1-3 g/10 min, wherein the propylene random copolymer has a melt flow rate of 0.1-0.3 g/10 min. ### Claim 14 (depends on 1) A method for preparing the propylene polymer composition according to claim 1, which comprises, in the presence of a Ziegler-Natta catalyst having high stereo-selectivity, two-step polymerization reactions as follows: copolymerizing propylene with ethylene and optionally one or more alpha-olefins of C4-C10 to obtain a propylene random copolymer; and homopolymerizing propylene to obtain a propylene homopolymer; wherein, the amounts of molecular weight regulator used in the two-step polymerization reactions are controlled so that the melt flow rate of the propylene random copolymer is lower than that of the propylene homopolymer; and the yield ratio of the copolymerization and homopolymerization of propylene is 30:70 to 70:30. ### Claim 15 (depends on 14) The method according to claim 14, wherein the two-step polymerization reactions are continuously carried out in at least two reaction zones in series. ### Claim 16 (depends on 14) A method according to claim 14, which comprises subjecting propylene to continuous random copolymerization and homopolymerization reactions in two loop reactors in series; wherein, in the presence of a Ziegler-Natta catalyst having high stereo-selectivity, the random copolymerization reaction of propylene and ethylene is carried out in the first loop reactor for a certain time, thereafter the reactants are transferred to the second loop reactor for carrying out the homopolymerization reaction of propylene; and wherein, a molecular weight regulator is added in different amounts to the first and second loop reactors, so that the MFR value of the propylene copolymer in the first stage is lower than that of the propylene homopolymer in the second stage; the yield ratio in the first and second loop reactors is about 65:35 to 55:45, the polymerization temperature in the two loop reactors is controlled in the range of 60-80° C., and the polymerization reactions are liquid phase bulk reactions. ### Claim 17 (depends on 14) A method according to claim 14, wherein the Ziegler-Natta catalyst having high stereo-selectivity comprises a Ti-containing active solid catalyst component, an organic aluminum compound as a co-catalyst component, and an organic silicon compound as an external electron donor component. ### Claim 18 (depends on 17) A method according to claim 17, wherein, in the Ziegler-Natta catalyst having high stereo-selectivity, the ratio of the organic aluminum compound as a co-catalyst component and the organic silicon compound as an external electron donor component, based on the molar ratio of Al/Si is 4-30. ### Claim 19 (depends on 1) An oriented film produced by the propylene polymer composition according to claim 1, which is single- or multi-layer, uni- or bi-axially oriented film, and the multi-layer oriented film has at least one layer containing said propylene polymer composition. ### Claim 20 (depends on 19) The film according to claim 19, wherein said oriented film is biaxially oriented film, and the biaxially oriented film has, in the absence of any stiffening agent, a transverse Young modulus of 5,000 MPa, and a longitudinal Young modulus of 2,400 MPa. ### Claim 21 (depends on 1) The propylene polymer composition according to claim 1, wherein the propylene polymer composition is prepared by a method which comprises, in the presence of a Ziegler-Natta catalyst having high stereo-selectivity, a two-step polymerization reaction as follows: copolymerizing propylene with ethylene and optionally one or more alpha-olefins of C4-C10 to obtain a propylene random copolymer; and homopolymerizing propylene to obtain a propylene homopolymer; wherein, the amounts of molecular weight regulator used in the two-step polymerization reactions are controlled so that the melt flow rate of the propylene random copolymer is lower than that of the propylene homopolymer; and the yield ratio of the copolymerization and homopolymerization of propylene is 30:70 to 70:30.