# US 7,611,698 B2 · Hair conditioning compositions > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 7,611,698 B2 - Document ID: US7611698B2 - Status: Granted - Kind: B2 - Application number: 10/514,219 - Filed: 2003-04-23 - Published: 2005-08-04 - Granted: 2009-11-03 - Earliest claimed: 2002-05-10 - Assignees: Unilever Home & Personal Care USA, Division of Conopco, Inc. - Inventors: Leo Derici; Paul David Jenkins; Andrew Malcolm Murray; Neil Scott Shaw - Web page: https://patentgrep.com/patent/US7611698B2 ## CPC - A61K 8/894: modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol - A61K 8/06: Emulsions - A61K 8/062: {Oil-in-water emulsions} - A61K 8/416: {Quaternary ammonium compounds (A61K8/35 takes precedence)} - A61K 8/891: saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone - A61K 8/898: containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine - A61K 8/90: Block copolymers (A61K8/89 takes precedence) - A61Q 5/12: Preparations containing hair conditioners - A61K 2800/412: Microsized, i.e. having sizes between 0.1 and 100 microns - A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D) - A61Q: SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS ## Abstract An aqueous hair conditioning composition comprising discrete, dispersed droplets of a hydrophobic conditioning oil with a mean droplet diameter (D3,2) of 4 micrometers or less, a cationic deposition polymer and a block copolymer of ethylene glycol and propylene glycol according to the Formula (I) with the mean value of y from 10 to 60 and the values of x and z both from 1 to 150, or a block copolymer according to Formula (II) wherein the mean value of a is 2 or more and the mean value of b is 2 or more. ## Claims ### Claim 1 A rinse off, aqueous hair conditioner composition comprising: a) discrete, dispersed droplets of a hydrophobic silicone conditioning oil with a mean diameter (D3,2) of 4 micrometers or less, b) from 0.01 to 5% by weight of a cationic deposition polymer and c) 0.04% to 1% by weight of a block copolymer, comprising polyethyleneoxide and polypropyleneoxide blocks, selected from the group consisting of: (i) poloxamers according to formula I: wherein said poloxamers are selected from the group consisting of: (ia) poloxamers according to formula I wherein the mean value of y is from 10 to 60 and the mean values of x and z are both from 1 to 20, and (ib) poloxamers according to formula I wherein the mean value of y is 35 and the mean values of x and z are both 52, and (ii) poloxamines according to formula II: wherein the mean value of a is 2 or more and the mean value of b is 2 or more, d) from 5 to 20% by weight of the hair conditioning composition of anionic cleansing surfactant; e) co-surfactant; and f) optionally, emulsifier; wherein: (A) the rinse off aqueous hair conditioner composition is in the form of a shampoo, (B) the hydrophobic silicone conditioning oil is added to the composition as a pre-formed aqueous emulsion that includes the block copolymer, and (C) the total amount of surfactant, including any co-surfactant and emulsifier, is from 10 to 25 percent by weight of the composition. ### Claim 2 (depends on 1) A composition according to claim 1 wherein the value of y is 40 or less. ### Claim 3 (depends on 1) A composition according to claim 1 wherein the hydrophobic silicone conditioning oil comprises a functionalised silicone. ### Claim 4 (depends on 3) A composition according to claim 3, wherein the functionalised silicone is an amino-functionalised silicone. ### Claim 5 (depends on 1) A composition according to claim 1 wherein the mean diameter of the droplets of hydrophobic silicone conditioning oil (D3,2) is 1 micrometer or less. ### Claim 6 (depends on 1) A composition according to claim 1 wherein the cationic deposition polymer is a cationic derivative of guar gum. ### Claim 7 (depends on 1) A method of selectively conditioning hair at the tips thereof, the method comprising the steps of: a) washing the hair with an aqueous hair conditioning composition according to claim 1, and b) rinsing the hair. ### Claim 8 (depends on 1) A composition according to claim 1 wherein the block copolymer comprises a poloxamine having a mean molecular weight of 4000 or more unified atomic mass units. ### Claim 9 (depends on 1) A composition according to claim 1 wherein the block copolymer comprises a poloxamine having a mean molecular weight of 6700 or more unified atomic mass units. ### Claim 10 (depends on 1) A composition according to claim 1 wherein the block copolymer comprises a poloxamine having a mean molecular weight of 8000 or more unified atomic mass units. ### Claim 11 (depends on 1) A composition according to claim 1 wherein the co-surfactant is selected from alkyl betaines, alkyl amidopropyl betaines and alkylsulphobetaines. ### Claim 12 (depends on 1) A composition according to claim 1 wherein the co-surfactant comprises cocamidopropyl betaine. ### Claim 13 (depends on 1) A composition according to claim 1 wherein the co-surfactant comprises a mono- or dialkyl alkanolamide co-surfactant. ### Claim 14 (depends on 1) A composition according to claim 1 wherein the block copolymer is present in an amount of 0.04 to 0.6% by weight of the composition. ### Claim 15 (depends on 1) A composition according to claim 1 wherein the block copolymer is present in an amount of 0.05 to 0.3% by weight of the composition. ### Claim 16 (depends on 1) A composition according to claim 1 wherein the mean value of y is from 10 to 40. ### Claim 17 (depends on 1) A composition according to claim 1 wherein the co-surfactant comprises at least one amphoteric or zwitterionic surfactant. ### Claim 18 (depends on 1) A composition according to claim 1 wherein the block copolymer is present in an amount of 0.04 to 0.6% by weight of the composition. ### Claim 19 A rinse off, aqueous hair conditioner composition comprising: a) discrete, dispersed droplets of a hydrophobic silicone conditioning oil with a mean diameter (D3,2) of 4 micrometers or less, b) from 0.01 to 5% by weight of a cationic deposition polymer, c) 0.04% to 0.6% by weight of a block copolymer, comprising polyethyleneoxide and polypropyleneoxide blocks, selected from the group consisting of: (i) poloxamers according to formula I: wherein the mean value of y is from 10 to 60 and the mean values of x and z are both from 1 to 150, and (ii) poloxamines according to formula II: wherein the mean value of a is 2 or more and the mean value of b is 2 or more, d) from 5 to 20% by weight of the hair conditioning composition of anionic cleansing surfactant; e) co-surfactant; and f) optionally, emulsifier; wherein: (A) the rinse off aqueous hair conditioner composition is in the form of a shampoo, (B) the hydrophobic silicone conditioning oil is added to the composition as a preformed aqueous emulsion that includes the block copolymer, and (C) the total amount of surfactant, including any co-surfactant and emulsifier, is from 10 to 25 percent by weight of the composition. ### Claim 20 (depends on 1) A composition according to claim 1 wherein the anionic cleansing surfactant is selected from the group consisting of alkyl sulphates, alkyl ether sulphates, alkaryl sulphonates, alkyl succinates, alkyl sulphosuccinates, alkyl phosphates, alkyl ether phosphates, alkyl ether carboxylates, the sodium magnesium, ammonium and mono-di, and triethanolamines salts thereof, and mixtures thereof, wherein the alkyl groups of such surfactants contain from 8 to 18 carbon atoms and may be unsaturated and wherein the alkyl ether sulphates, alkyl ether phosphates and alkyl ether carbonates may contain from 1 to 10 ethylene oxide or propylene oxide units per molecule.