# US 7,608,326 B2 · Thermally conductive EMI shield > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 7,608,326 B2 - Document ID: US7608326B2 - Status: Granted - Kind: B2 - Application number: 10/531,890 - Filed: 2003-10-21 - Published: 2006-05-11 - Granted: 2009-10-27 - Earliest claimed: 2002-10-21 - Assignees: Laird Technologies, Inc. - Inventors: Richard Norman Johnson - Web page: https://patentgrep.com/patent/US7608326B2 ## CPC - H05K 7/20481: {characterised by the material composition exhibiting specific thermal properties} - H05K 9/0083: {comprising electro-conductive non-fibrous particles embedded in an electrically insulating supporting structure, e.g. powder, flakes, whiskers (H05K9/0086 takes precedence)} - H10W 40/251: {Organics} - H10W 40/257: {having a heterogeneous or anisotropic structure, e.g. powder or fibres in a matrix, wire mesh or porous structures (H10W40/254, H10W40/251 take precedence)} - H10W 42/20: protecting against electromagnetic or particle radiation, e.g. light, X-rays, gamma-rays or electrons - H10W 42/287: {materials for magnetic shielding, e.g. ferromagnetic materials} - H10W 72/877: {Bump connectors and die-attach connectors} - H10W 90/736: {between a chip and a stacked lead frame, conducting package substrate or heat sink} - Y10T 428/25: Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles - Y10T 428/256: Heavy metal or aluminum or compound thereof - Y10T 428/257: Iron oxide or aluminum oxide - Y10T 428/26: Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension - Y10T 428/31551: Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.] - Y10T 428/31801: Of wax or waxy material - Y10T 428/31855: Of addition polymer from unsaturated monomers - Y10T 428/32: Composite [nonstructural laminate] of inorganic material having metal-compound-containing layer and having defined magnetic layer - H05K: PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS - H10W: GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10 - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract Electromagnetic-energy absorbing materials are combined with thermally conductive materials, such as those used for thermal management in association with electronic equipment, thereby suppressing the transmission of electromagnetic interference (EMI) therethrough. Disclosed are materials and processes for combining EMI-absorbing materials with thermally conductive materials thereby improving EMI shielding effectiveness in an economically efficient manner. In one embodiment, a thermally conductive EMI absorber is prepared by combining an EMI-absorbing material (for example, ferrite particles) with a thermally conducting material (for example, ceramic particles), each suspended within an elastomeric matrix (for example, silicone). In application, a layer of thermally conductive EMI-absorbing material is applied between an electronic device or component, and a heat sink ## Claims ### Claim 1 A thermally conductive composite material for reducing electromagnetic emissions generated by an electronic device, said thermally conductive composite material comprising: a thermally conductive material in particulate form; and an electromagnetic-energy-absorptive material in particulate form, said thermally conductive material and said electromagnetic-energy-absorptive material being suspended within a polymeric base material, said polymeric base material being substantially transparent to electromagnetic energy, said polymeric base material comprising a phase-change material and up to 19.35% by weight of ethylene-vinyl acetate, the phase-change material comprising a paraffin wax or a synthetic wax, wherein the phase-change material has a reflow temperature that allows the thermally conductive material in particulate form that is suspended within the polymeric base material to flow into gaps and thereby at least reduce thermal impedance, wherein said thermally conductive composite material is configured such that when placed between an electronic device and a proximate structure, said thermally conductive material is operable for facilitating transfer of thermal energy from said electronic device and said electromagnetic-energy-absorptive material is operable for reducing electromagnetic emissions generated by the device, and wherein the electromagnetic-energy-absorptive material includes carbonyl iron. ### Claim 2 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein at least one of said thermally conductive material and said electromagnetic-energy-absorptive material comprises particles in the form of granules having a spheroid shape. ### Claim 3 (depends on 2) A thermally conductive composite material as claimed in claim 2 wherein the thermally conductive material comprises microspheres. ### Claim 4 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said thermally conductive material is selected from the group consisting of aluminum nitride, boron nitride, iron, metallic oxides and combinations thereof. ### Claim 5 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said thermally conductive material is a ceramic material. ### Claim 6 (depends on 1) A thermally conducting composite material as claimed in claim 1 wherein said polymeric base material has a relative dielectric constant of less than approximately 4 and a loss tangent of less than approximately 0.1. ### Claim 7 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material is selected from the group consisting of elastomers, natural rubbers, synthetic rubbers, PDP, EPDM rubber, and combinations thereof. ### Claim 8 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material is selected from the group consisting of silicone, fluorosilicone, isoprene, nitrile, chlorosulfonated polyethylene, neoprene, fluoroelastomer, urethane, thermoplastics, thermoplastic elastomer (TPE), polyamide TPE, thermoplastic polyurethane (TPU), and combinations thereof. ### Claim 9 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material is a solid material selected from the group consisting of thermoplastic and thermosetting materials. ### Claim 10 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material is a liquid. ### Claim 11 (depends on 10) A thermally conductive composite material as claimed in claim 10 wherein said liquid is selected from the group consisting of silicones, epoxies, polyester resins, and combinations thereof. ### Claim 12 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a phase-change material configured to exist in a solid phase at ambient room temperature and transition to a liquid phase at a reflow temperature. ### Claim 13 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a mixture of a paraffin wax and an ethylene-vinyl acetate copolymer. ### Claim 14 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a synthetic wax having a melting point of approximately 100° C. and a molecular weight of approximately 1000. ### Claim 15 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said electromagnetic-energy-absorptive material has a relative magnetic permeability greater than about 3.0 at approximately 1.0 GHz and greater than about 1.5 at 10GHz. ### Claim 16 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said composite material is in the form of a sheet having a thickness greater than approximately 0.01 inches. ### Claim 17 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said composite material is in the form of a sheet having a thickness less than approximately 0.18 inches. ### Claim 18 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said composite material is in the form of a sheet, and further comprises an adhesive on at least one side of said sheet. ### Claim 19 (depends on 18) A thermally conductive composite material as claimed in claim 18 wherein said adhesive is a thermoconductive adhesive. ### Claim 20 (depends on 18) A thermally conductive composite material as claimed in claim 18 wherein said adhesive is a pressure-sensitive, thermally conductive adhesive. ### Claim 21 (depends on 18) A thermally conductive composite material as claimed in claim 18 wherein said adhesive is based on compounds selected from the group consisting of acrylics, silicones, rubbers and combinations thereof. ### Claim 22 (depends on 18) A thermally conductive composite material as claimed in claim 18 wherein said adhesive further comprises a ceramic powder. ### Claim 23 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein the electromagnetic-energy-absorptive material includes generally ellipsoidal carbonyl iron granules. ### Claim 24 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein the electromagnetic-energy-absorptive material is entirely carbonyl iron. ### Claim 25 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein: the electromagnetic-energy-absorptive material exhibits better thermal conductivity than air; and the thermally conductive material exhibits greater thermal conductivity than the electromagnetic-energy-absorptive material, the thermally conductive material having a thermal impedance value substantially less than that of air. ### Claim 26 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein the composite material includes about 60 percent by volume of the thermally conductive material and the electromagnetic-energy-absorptive material. ### Claim 27 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein: the thermally conductive material in particulate form comprises granules spaced-apart from each other; the electromagnetic-energy-absorptive material in particulate form comprises granules spaced apart from each other and spaced-apart from the granules of the thermally conductive material; and the composite material is electrically non-conductive. ### Claim 28 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a mixture of 25 parts by weight of a paraffin wax and 6 parts by weight of an ethylene-vinyl acetate copolymer. ### Claim 29 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a mixture of 95 parts by weight of a paraffin wax and 5 parts by weight of an ethylene-vinyl acetate copolymer. ### Claim 30 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a mixture of a paraffin wax in an amount of about 80.65% by weight and an ethylene-vinyl acetate copolymer in an amount of about 19.35% by weight. ### Claim 31 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a mixture of a paraffin wax in an amount of about 95% by weight and an ethylene-vinyl acetate copolymer in an amount of about 5% by weight. ### Claim 32 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a mixture of a paraffin wax in an amount of between about 80.65% and about 95% by weight and an ethylene-vinyl acetate copolymer in an amount of between about 5% and about 19.35% by weight. ### Claim 33 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a mixture of paraffin wax having a melting point of approximately 51 degrees Celsius and a 28% ethylene-vinyl acetate copolymer having a melting point of approximately 74 degrees Celsius. ### Claim 34 (depends on 1) An electronic component comprising an integrated circuit, a heat sink, and the composite material of claim 1. ### Claim 35 A method of reducing electromagnetic emissions produced by a device comprising: combining a thermally conductive material in particulate form with an electromagnetic-energy-absorptive material in particulate form, the electromagnetic-energy-absorptive material including carbonyl iron; suspending the combined thermally conductive material and electromagnetic-energy-absorptive material in a polymeric base material comprising a phase-change material and up to 19.35% by weight of ethylene-vinyl acetate, the phase-change material comprising a paraffin wax or a synthetic wax; and placing the combined thermally conductive material and electromagnetic-energy-absorptive material suspended in the polymeric base material between said device and a proximate structure, wherein the phase-change material has a reflow temperature that allows the thermally conductive material in particulate form suspended within the polymeric base material to flow into gaps and thereby at least reduce thermal impedance between the device and the proximate structure. ### Claim 36 (depends on 35) The method of claim 35 wherein the proximate structure comprises a heat sink. ### Claim 37 (depends on 35) The method of claim 35 wherein said device comprises an integrated circuit. ### Claim 38 (depends on 35) The method of claim 35 wherein: the combined thermally conductive material and electromagnetic-energy-absorptive material suspended in the polymeric base comprise a liquid solution; and placing comprises applying the liquid solution onto a surface of at least one of the device and the proximate structure having one or more surface imperfections, and allowing the liquid solution to flow into the one or more surface imperfections. ### Claim 39 (depends on 35) The method of claim 35 wherein: the combined thermally conductive material and electromagnetic-energy-absorptive material suspended in the polymeric base comprise a liquid solution; and placing comprises spraying or painting the liquid solution onto a surface of at least one of the device and the proximate structure. ### Claim 40 (depends on 35) The method of claim 35 wherein said polymeric base material comprises a mixture of 25 parts by weight of a paraffin wax and 6 parts by weight of an ethylene-vinyl acetate copolymer. ### Claim 41 (depends on 35) The method of claim 35 wherein said polymeric base material comprises a mixture of 95 parts by weight of a paraffin wax and 5 parts by weight of an ethylene-vinyl acetate copolymer. ### Claim 42 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein: the composite material is in the form of a sheet having a thickness of about 0.125 inch and exhibits an attenuation of at least about 5 dB in a frequency range from about 5 GHz up to at least about 18 GHz; or the composite material is in the form of a sheet having a thickness of about 0.02 inch and exhibits an attenuation of at least about 3 dB for a frequency range extending upward from about 10 GHz; or the composite material is in the form of a sheet having a thickness of about 0.04 inch and exhibits an attenuation of at least about 10 dB in a frequency range from about 9 GHz up to at least about 15 GHz and an attenuation of at least about 6 dB in a frequency range extending upward from about 15 GHz; or the composite material is in the form of a sheet having a thickness of about 0.060 inch and exhibits an attenuation of at least about 5 dB in a frequency range extending upward from about 4 GHz, having a greater attenuation of at least about 10 dB in a frequency range from about 6 GHz up to at least about 10 GHz. ### Claim 43 (depends on 1) A thermally conductive composite material as claimed in claim 1 wherein said polymeric base material comprises a mixture of a paraffin wax and an ethylene-vinyl acetate copolymer, including an amount of the paraffin wax within a range of from about 25 parts by weight paraffin wax to 6 parts by weight ethylene-vinyl acetate copolymer, up to about 95 parts by weight paraffin wax and 5 parts by weight of ethylene-vinyl acetate copolymer.