# US 7,608,176 B2 · Gas concentration detecting apparatus > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 7,608,176 B2 - Document ID: US7608176B2 - Status: Granted - Kind: B2 - Application number: 10/681,138 - Filed: 2003-10-09 - Published: 2004-04-22 - Granted: 2009-10-27 - Earliest claimed: 2002-10-10 - Assignees: Denso Corporation - Inventors: Mitsunobu Niwa - Web page: https://patentgrep.com/patent/US7608176B2 ## CPC - G01N 27/419: Measuring voltages or currents with a combination of oxygen pumping cells and oxygen concentration cells - G01N 27/4071: {using sensor elements of laminated structure} - G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q) ## Abstract The present invention relates a gas concentration detecting apparatus capable of appropriately making a decision on activation of each of a pump cell, a monitor cell and a sensor cell of its gas concentration sensor. In the apparatus, a control circuit outputs an oxygen concentration value on the basis of a current flowing when a voltage is applied to the pump cell and outputs an NOx concentration value on the basis of a current flowing at the voltage application to the sensor cell. Moreover, the control circuit separately makes a decision on activation of the pump cell and a decision on activation of the sensor cell in the middle of the activation of the sensor. Still moreover, the control circuit makes the decision on the activation of the sensor cell after the activation of the pump cell reaches completion. ## Claims ### Claim 1 A gas concentration detecting apparatus comprising: a gas sensor further comprising: a first cell for detecting a concentration of oxygen in a measurement gas, the first cell having a first chamber and a pair of first electrodes, discharging or pumping in oxygen contained in the measurement gas introduced from an external space into the first chamber to generate a pumped measurement gas which contains an excessive oxygen and to output a first electric current indicating the concentration of oxygen in the measurement gas when a first electric voltage is applied between the pair of the first electrodes; and a second cell for detecting a concentration of a specific gas in the pumped measurement gas, the second cell having a second chamber and a pair of second electrodes and decomposing the specific gas contained in the pumped measurement gas which is generated by the first cell and is introduced from the first chamber into the second chamber to output a second electric current indicating a concentration of the specific gas in the measurement gas when a second electric voltage is applied between the pair of the second electrodes; and a controller that determines a completion of activation of the first cell for allowing to start making use of the first electric current at a first time moment at which a first predetermined period of time elapses after the electric power has been started to be supplied to the first and the second cells to activate at least the one of the first cell and the second cell, and determines a completion of activation of the second cell for allowing to start making use of the second electric current when the second electric current flowing in the second cell of the gas sensor is fallen into a predetermined range and when a predetermined time elapses. ### Claim 2 (depends on 1) The gas concentration detecting apparatus according to claim 1, wherein the controller determines the second time moment at which the controller determines that the activation of the second cell is completed when a second predetermined period of time elapses after the activation of the first cell has been completed. ### Claim 3 (depends on 2) The gas concentration detecting apparatus according to claim 2, wherein the second predetermined period of time is determined on the basis of a time needed for discharging all oxygen absorbed onto one of the second electrodes of said second cell. ### Claim 4 (depends on 1) The gas concentration detecting apparatus according to claim 1, wherein the first cell comprises a first solid electrolyte element which is sandwiched between the first electrodes, and the second cell comprises a second solid electrolyte element which is sandwiched between the second electrodes, further comprising: an element resistance monitor for monitoring a resistance value of at least one of the first and second solid electrolyte element to control a degree of activation of the cell in order to keep the resistance value of the corresponding solid electrolyte element at a first predetermined target value after starting energization of the gas concentration sensor, wherein the controller determines the completion of the activation of the first cell for allowing to start making use of the first electric current when the monitored resistance value of the solid electrolyte element which is monitored by the element resistance monitor becomes a second predetermined target value. ### Claim 5 (depends on 4) The gas concentration detecting apparatus according to claim 4, wherein the controller determines a completion of activation of the first cell for allowing to start making use of the first electric current, when the monitored resistance value of the solid electrolyte element which is monitored by the element resistance monitor is within a predetermined range, and a predetermined time elapses after the monitored resistance value of the solid electrolyte element which is monitored by the element resistance monitor has been within the predetermined range. ### Claim 6 (depends on 4) The gas concentration detecting apparatus according to claim 4, wherein the controller determines a completion of activation of the first cell for allowing to start making use of the first electric current, when the monitored resistance value of the solid electrolyte element which is monitored by the element resistance monitor becomes a second predetermined target value, and a predetermined time elapses after the monitored resistance value of the first solid electrolyte element which is monitored by the element resistance monitor has become the second predetermined target value. ### Claim 7 (depends on 1) The gas concentration detecting apparatus according to claim 1, further comprising: a heater that heats up at least one of the first cell and the second cell to activate the one of the first cell and the second cell when an electric power is supplied to the heater, and wherein the controller that determines the completion of activation of the first cell for allowing to start making use of the first electric current at a first time moment at which a predetermined period of time elapses after the electric power has been started to be supplied to the heater to activate at least the one of the first cell and the second cell. ### Claim 8 (depends on 1) The gas concentration detecting apparatus according to claim 1, wherein the predetermined period of time is determined on the basis of a time needed for discharging all oxygen absorbed onto one of the second electrodes of said second cell. ### Claim 9 (depends on 1) The apparatus according to claim 1, wherein the first electrodes of the first cell is reactively inactive with respect to the specific gas, and the second electrodes of the second cell is reactively active with respect to the specific gas. ### Claim 10 (depends on 1) The apparatus according to claim 1, further comprising: a third cell for detecting a residual oxygen concentration of said measuring gas after passing through said first cell, wherein an amplitude of said first voltage to be applied to said first cell from the power supply is variably controlled on the basis of a detection result in said third cell. ### Claim 11 A gas concentration detecting apparatus comprising: a gas sensor further comprising: a first cell for detecting a concentration of oxygen in a measurement gas, the first cell having a first chamber and a pair of first electrodes, discharging or pumping in oxygen contained in the measurement gas introduced from an external space into the first chamber to generate a pumped measurement gas which contains an excessive oxygen and to output a first electric current indicating the concentration of oxygen in the measurement gas when a first electric voltage is applied between the pair of the first electrodes; a second cell for detecting a concentration of a specific gas in the pumped measurement gas, the second cell having a second chamber and a pair of second electrodes and decomposing the specific gas contained in the pumped measurement gas which is generated by the first cell and is introduced from the first chamber into the second chamber to output a second electric current indicating a concentration of the specific gas in the measurement gas when a second electric voltage is applied between the pair of the second electrodes; and a third cell for detecting a residual oxygen concentration of said measuring gas after passing through said first cell, the third cell outputting a third electric current indicating the residual oxygen concentration in the measurement gas when a third electric voltage is applied thereto; and a controller that determines a completion of activation of the first cell for allowing to start making use of the first electric current at a first time moment at which a first predetermined period of time elapses after the electric power has been started to be supplied to at least the first and the second cells to activate at least the one of the first cell and the second cell, and determines a completion of activation of the second cell for allowing to start making use of the second electric current when the third electric current flowing in the third cell of the gas sensor is fallen into a predetermined range and when a predetermined time elapses. ### Claim 12 (depends on 11) The gas concentration detecting apparatus according to claim 11, wherein the first cell comprises a first solid electrolyte element which is sandwiched between the first electrodes, the second cell comprises a second solid electrolyte element which is sandwiched between the second electrodes, and third cell comprises a third solid electrolyte element, further comprising: an element resistance monitor for monitoring a resistance value of at least one of the first, second, and third solid electrolyte element to control a degree of activation of the cell in order to keep the resistance value of the corresponding solid electrolyte element at a first predetermined target value after starting energization of the gas concentration sensor, wherein the controller determines the completion of the activation of the first cell for allowing to start making use of the first electric current when the monitored resistance value of the solid electrolyte element which is monitored by the element resistance monitor becomes a second predetermined target value. ### Claim 13 (depends on 12) The gas concentration detecting apparatus according to claim 12, wherein the controller determines a completion of activation of the first cell for allowing to start making use of the first electric current, when the monitored resistance value of the solid electrolyte element which is monitored by the element resistance monitor is within a predetermined resistance range, and a predetermined time elapses after the monitored resistance value of the solid electrolyte element which is monitored by the element resistance monitor has been within the predetermined range. ### Claim 14 (depends on 12) The gas concentration detecting apparatus according to claim 12, wherein the controller determines a completion of activation of the first cell for allowing to start making use of the first electric current, when the monitored resistance value of the solid electrolyte element which is monitored by the element resistance monitor becomes a second predetermined target value, and a predetermined time elapses after the monitored resistance value of the first solid electrolyte element which is monitored by the element resistance monitor has become the second predetermined target value. ### Claim 15 (depends on 11) The gas concentration detecting apparatus according to claim 11, further comprising: a heater that heats up at least one of the first cell and the second cell to activate the one of the one of the first, second, and third cell when an electric power is supplied to the heater, and wherein the controller that determines the completion of activation of the first cell for allowing to start making use of the first electric current at a first time moment at which a predetermined period of time elapses after the electric power has been started to be supplied to the heater to activate at least the one of the first, second, and third cell.