# US 7,608,143 B2 · Methods of reducing hydroxyl ions in concrete pore solutions

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- Number: US 7,608,143 B2
- Document ID: US7608143B2
- Status: Granted
- Kind: B2
- Application number: 11/157,559
- Filed: 2005-06-21
- Published: 2006-03-02
- Granted: 2009-10-27
- Earliest claimed: 2004-10-25
- Inventors: Paul W. Brown
- Web page: https://patentgrep.com/patent/US7608143B2

## CPC

- C04B 41/009: {characterised by the material treated}
- C04B 28/02: containing hydraulic cements other than calcium sulfates
- C04B 41/4922: {applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane}
- C04B 41/64: Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
- C04B 2111/2023: {Resistance against alkali-aggregate reaction}
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE

## Abstract

Methods of reducing hydroxyl ions in concrete pore solutions are provided. Such methods are useful in providing resistance to gels which form in concrete due to the alkali-silica (ASR) reaction. The methods comprise, in one aspect, adding a salt, in aqueous or solid form, to the concrete, the salt having a cation higher in valence than the anion. In other aspects, the methods of the present invention comprise adding an acidic phosphate or a silicon-containing alkoxide to the concrete. All of the above methods are useful in reducing hydroxyl ions in concrete. Such methods can be used to resist ASR in fresh concrete, in concrete that is setting, or in hardened concrete. Methods are also provided for mitigating ASR while simultaneously healing cracks in concrete or bonding new concrete to existing concrete. The methods involve reacting an Si-containing alkoxide with a source of reactive calcium to produce calcium silicate hydrate.

## Claims

### Claim 1

A method of bonding new concrete to existing setting or hardened concrete, the method comprising introducing an Si-containing alkoxide to the existing concrete such that the Si-containing alkoxide at least partially infiltrates the existing concrete and casting the new concrete over the Si-containing alkoxide and existing concrete, said Si-containing alkoxide selected from the group consisting of tetraethyloxysilane, tetramethyloxysilane and an ethyl polysilicate, wherein the Si-containing alkoxide reacts with a source of calcium to form calcium silicate hydrate that bonds the new concrete to the existing concrete.

### Claim 2 (depends on 1)

The method of claim 1, wherein SiO2 content of the Si-containing alkoxide ranges from about 1 to 45 weight percent.

### Claim 3 (depends on 1)

The method of claim 1, wherein the Si-containing alkoxide participates in a reaction to produce a reactive form of silica selected from the group consisting of anhydrous silica, silicate oligomers, silica hydroxides, and combinations thereof.

### Claim 4 (depends on 1)

The method of claim 1, wherein the Si-containing alkoxide undergoes hydrolysis and condensation reactions.

### Claim 5 (depends on 4)

The method of claim 4, further comprising introducing a co-solvent to the existing concrete such that the co-solvent at least partially infiltrates the existing concrete to control rates of hydrolysis and condensation.

### Claim 6 (depends on 4)

The method of claim 4, further comprising adjusting reaction temperature to control rates of hydrolysis and condensation.

### Claim 7 (depends on 4)

The method of claim 4, further comprising introducing colloidal silica to the existing concrete such that the colloidal silica at least partially infiltrates the existing concrete to increase viscosity of the Si-containing alkoxide.

### Claim 8 (depends on 4)

The method of claim 4, further comprising introducing an acid to the existing concrete such that the acid at least partially infiltrates the existing concrete to control rates of hydrolysis and condensation.

### Claim 9 (depends on 4)

The method of claim 4, further comprising introducing a base to the existing concrete such that the base at least partially infiltrates the existing concrete to control rates of hydrolysis and condensation.

### Claim 10 (depends on 9)

The method of claim 9, wherein the base is an alkali silicate.

### Claim 11 (depends on 1)

The method of claim 1, wherein the Si-containing alkoxide is diluted with alcohol.

### Claim 12 (depends on 1)

The method of claim 1, further comprising introducing a compound to the existing concrete such that the compound at least partially infiltrates the existing concrete, the compound being selected from the group consisting of lithium polysilicate and a lithium alkoxide.