Method for the production of organic carbonates
AssigneeLurgi GmbH
InventorsHenning Buchold, Jürgen Eberhardt, Ulrich Wagner, Hans-Jörg Wölk
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AssigneeLurgi GmbH
InventorsHenning Buchold, Jürgen Eberhardt, Ulrich Wagner, Hans-Jörg Wölk
Estimating the term…
The invention relates to a method for the production of monomer organic carbonates from a mixture of organic carbonates and carbamates which are obtained by reacting urea, substituted urea, a salt or ester of carbamide acid or one of the N-substituted derivatives thereof with a polyalkylene glycol, polyester-polyol or a polyether-polyol of general formula (I), wherein R represents a linear or branched alkylene group having 2-12 carbon atoms and n represents a number between 2 and 20, or with a completely or partially hydrolysed polyvinyl alcohol of general formula (II), wherein R′ represents an alkyl group, an aryl group or an acyl group having 1-12 carbon atoms, p and q represent a number between 120, or with mixtures of said compounds in the presence of a catalyst facilitating the separation of ammonia and the ammonia becomes free or the amine is removed from the reaction mixture by means of a strip gas, whereby said mixture is reacted with an alcohol or a phenol whereby monomer carbonates are formed and polymer polyalcohols of formulae (I) or (II) are reformed.
A method for the manufacture of an organic carbonate from a mixture of polymeric polyalcohols and their carbonates and carbamates, which through reaction of urea, a substituted urea, a salt or ester of carbamic acid or one of their N-substituted derivatives with a polyalkylkeneglycol, polyesterpolyol or a polyetherpolyol of general formula I
Dependencies are inferred from the claim text.