Processes for the production of xylitol
AssigneePurdue Research Foundation
InventorsJames N. BeMiller, Jonathan A. Stapley
Life of this patent
Estimating the term…
Abstract
Methods of producing xylitol comprising the oxidative decarboxylation of a reactant substrate are provided herein. The oxidative decarboxylation is performed in one of two ways. In the first, the oxidative decarboxylation is performed by an electrochemical process, preferably an anodic odixative decarboxylation of a reactant substrate. In the second, the oxidative decarboxylation of the reactant substrate is carried out by a series of oxidation-reduction chemical reactions.
Claims14
A method of producing xylitol, comprising the steps of:
- a. electrochemically oxidatively decarboxylating a uronic acid compound to produce a dialdehydo xylitol intermediate, and
- b. hydrogenating the xylitol intermediate to produce xylitol.
A method of producing xylitol comprising the following steps:
- a. hydrolyzing a D-glucuronic acid compound,
- b. decarboxylating a salt of the D-glucuronic acid compound to produce a dialdehydo xylitol intermediate, and
- c. hydrogenating the dialdehydo xylitol intermediate in the presence of a hydrogenation catalyst to produce xylitol.
A method of producing xylitol comprising the steps of:
- a. providing a D-glucopyranosyl-containing material,
- b. oxidizing the D-glucopyranosyl-containing material to form a precursor material comprising a D-glucuronopyranosyl moiety,
- c. hydrolyzing the precursor material containing the D-glucuronopyranosyl moiety to form a reactant substrate comprising D-glucuronic acid,
- d. electrochemically oxidatively decarboxylating the reactant substrate comprising D-glucuronic acid to produce a dialdehydo xylitol intermediate;
- and
- e. reducing and hydrogenating the dialdehydo xylitol intermediate to produce xylitol.
A method of producing xylitol comprising the steps of:
- a. electrochemically decarboxylating a D-glucuronic acid compound to produce a dialdehydo xylitol intermediate;
- and
- b. hydrogenating the dialdehydo xylitol intermediate in the presence of a catalyst to produce xylitol.
A method of producing xylitol comprising the steps of:
- a. electrochemical decarboxylation of a uronic acid compound to produce a dialdehydo xylitol intermediate, and
- b. hydrogenating the dialdehydo xylitol intermediate in the presence of a catalyst to produce a mixture of xylitol and D-arabinitol.
A method of producing xylitol comprising the steps of:
- a. providing a D-glucopyranosyl-containing starting material;
- b. oxidizing the D-glucopyranosyl-containing starting material to form a reactant substrate comprising a D-glucuronopyranosyl moiety;
- c. electrochemically decarboxylating the reactant substrate containing the D-glucuronopyranosyl moiety to form a dialdehydo xylitol intermediate;
- d. reducing and hydrogenating the dialdehydo xylitol intermediate to produce xylitol.
Dependencies are inferred from the claim text.