Metal component for fuel cell and method of manufacturing the same, austenitic stainless steel for polymer electrolyte fuel cell and metal component for fuel cell material and method of manufacturing the same, corrosion-resistant conductive component and method of manufacturing the same, and fuel cell
An Au plated film 12 is formed on the surface of a plate-formed metal base 13 composed of a metal less noble than Au, and the product is cut along a planned cutting line 18 reflecting a contour of a desired component, to thereby form a separator 10. Thus-formed separator 10 has the Au plated film 12 formed on the main surface 10a thereof, and has a cutting plane 16 formed as an end face 16 stretched up to the main surface 10a. The metal base 13 exposes in a part of the cutting plane 16, in a width of the exposed region of 1 mm or less. This is successful in providing a metal component for fuel cell which is satisfactory in the corrosion resistance and allows easy fabrication at low costs, a method of manufacturing the same, and also in providing a fuel cell having thus-fabricated metal component for fuel cell.
Drawings
Claims15
A metal component for fuel cell, to be disposed in contact with a main cell unit comprising a polymer electrolyte film and a pair of electrodes holding it in between,
configured as having a plate-formed metal base composed of a metal less noble than Au, and an Au film formed on a main surface thereof, wherein the metal base is provided with a cutting plane, wherein an end face is formed by the cutting plane such that the Au film is extended along the end face so as to cover part of the end face, the endface having a region of 1 mm or less in width where the metal base is exposed.
A metal component for fuel cell, to be disposed in contact with a main cell unit comprising a polymer electrolyte film and a pair of electrodes holding it in between,
configured as having an Au film formed on the main surface of a plate-formed metal base composed of a metal less noble than Au, and said metal base being cut along a planned cutting line forming a contour of said component, wherein an end face formed by the cutting process has a region of 1 mm or less in width were the metal base is exposed.
A polymer electrolyte fuel cell material comprising a plate material composed of an Fe-base alloy, Ni-base alloy, Ti or Ti-base alloy, and a cover film of a noble metal covering the surface thereof, wherein the cover film on the plate material has a surface roughness as expressed in Rmax of 1.5 μm or less.
A corrosion-resistant conductive component comprising a metal base and a noble metal film of 100 nm thick or less formed on at least a part of the surface of said metal component, said noble metal layer and an intermediate layer formed between said base and said noble metal layer having impurity contents of C:
6 Jun 2025Estimated · howhide20 years from earliest known nonprovisional domestic filing plus recorded patent term adjustment, including 657 days of adjustment. Maintenance-fee lapses, terminal disclaimers and statutory extensions have not been checked. The continuity chain may be incomplete; this is not an enforceability determination.
Characterised by the form: corrugated or undulated
Life of this patent
Term ended 6 Jun 2025 (estimated)
Priority, Japan20 Aug 2002
Filed19 Aug 2003
Published20 Jul 2006
Granted6 Oct 2009
Term ended6 Jun 2025
Priority, Japan20 Aug 2002
Granted6 Oct 2009
Term ended6 Jun 2025
Priority claimedJP 2002-239723
Application filedUS 10/525,234
Assigned to Daido Tokushuko Kabushiki Kaishaassignment of assignor's interest
PublishedUS 2006/0159971 A1
GrantedUS 7,597,987 B2
Term endedEstimated, includes 657 days of adjustment
Description20,385 words
Summary9,495 words
#A first invention relates to a metal component for fuel cell and a method of manufacturing the same, and also to a fuel cell.
#A second invention relates to an austenitic stainless steel for polymer electrolyte fuel cell, and more specifically to an austenitic stainless steel for polymer electrolyte fuel cell used for conductive separator, current collector and so forth, and a metal component for fuel cell using the same, and also to a fuel cell.
#A third invention relates to a polymer electrolyte fuel cell material such as a metal separator, current collector plate and so forth used in polymer electrolyte fuel cell, and a method of manufacturing the same, and also to a metal component for fuel cell using the same and a fuel cell.
Brief description of the drawings22 figures
#FIG. 1 is a schematic drawing showing an exemplary configuration of a fuel cell of the first invention;
#FIG. 2A is a first schematic drawing showing an exemplary configuration of a metal component for fuel cell of the first invention;
#FIG. 2B is a second schematic drawing showing an exemplary configuration of the metal component for fuel cell of the first invention;
Detailed description10,464 words
#FIG. 1 explains the outlines of a metal separator for fuel cell commonly applicable to the first, second, third and fourth inventions, and an exemplary mode of a fuel cell using the same. The fuel cell 1 is a polymer electrolyte fuel cell adopting a polymer electrolyte film 3. More specifically, the polymer electrolyte film 3 may be composed of a fluorine-containing resin containing sulfonic acid groups. The fuel cell 1 has a polymer electrolyte film 3 and a pair of electrodes 2, 4 holding it in between, and therefore has a main cell unit 5 which comprises the polymer electrolyte film 3 and the electrodes 2, 4. The electrodes 2, 4 are brought into contact with the polymer electrolyte film 3 on their first main surfaces 2a, 4a, and plate-formed separators 10 are disposed on the outer sides of the electrodes 2, 4 so as to be brought into contact therewith on their second main surfaces 2b, 4b. Each of the separators 10 plays a role of connecting the main cell units 5 in series, and is disposed so as to supply a fuel gas and oxidizer gas to the main cell unit 5. In this mode of embodiment, the separator 10 corresponds to a metal component for fuel gas of the first invention. It is to be noted that a gasket, not shown in FIG. 1, is disposed between the main cell unit 5 and each of the separators 10 in order to prevent leakage of the fuel gas and oxidizer gas. The main cell unit 5 and the separators 10 composes a unit cell U, and a plurality of the unit cells U are stacked while individually placing a cooling water flowing substrate 11 (composed of a conductive material such as graphite) in between, to thereby configure a fuel cell stack 1. The unit cells U are stacked in, for example, the number of 50 to 400 or around, and respectively on both ends of the stack, there are disposed, as viewed from the side in contact with the unit cell U, a conductive sheet 9, a current collector plate 8, an insulating sheet 7, and a tightening plate 6, to thereby configure a fuel cell stack 1. The current collector plate 8 and a plurality of separators 10 are connected in series, so as to collect current from a plurality of main cell units 5. It is defined now that the above-described unit cell U and fuel cell stack 1 are also included in the concept of the fuel cell in this patent specification. It is to be noted that FIG. 1 shows the individual components, including the conductive sheet 9, current collector plate 8, insulating sheet 7 and tightening plate 6, are illustrated as being departed from each other, but these components in practice are tightened with each other using bolts, for example.
#FIG. 2A to FIG. 2C show the outlines of the separator 10. As shown in FIG. 2A, the separators 10 are shaped in a plate form, have a regular rough formed on the main surfaces thereof, and are disposed so as to make the end sides of the projected portions 14 of the separators 10 contact with the electrodes 2, 4. The recessed portions of each separator 10 serve as gas a flow path 21 (see also FIG. 1) through which a fuel gas or an oxidizer gas is supplied to the electrodes 2, 4. The gas flow path 21 has openings formed on both ends thereof, which serve as a reaction gas inlet port 22 and a reaction gas outlet port 23, respectively. The separators 10 are stacked so that the reaction gas inlet ports 22 and reaction gas outlet ports 23 formed on the individual separators 10 are aligned at the same positions.
#The paragraphs below will describe modes of embodiments specific to the individual inventions.