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US 7,597,874 B1Granted
Preparation of zeolites using novel structure directing agents
AssigneeChevron U.S.A. Inc.
InventorsStephen J. Miller, Lun-Teh Yuen
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Abstract
The present invention is directed to a process for producing crystalline zeolites from a reaction mixture containing an N,N,N-trialkyl benzyl quaternary ammonium cation as a structure directing agent.
Claims20
A method for preparing a zeolite having a CHA framework topology, comprising the steps of:
- (1) preparing an aqueous reaction mixture comprising:
- (a) at least one active source of an oxide of a tetravalent element,
- (b) at least one active source of an oxide of a trivalent element, a pentavalent element, a second tetravalent element which is different from the first tetravalent element, or a mixture thereof,
- (c) at least one active source of an element selected from Groups 1 and 2 of the Periodic Table,
- (d) water as a solvent,
- (e) seed crystals capable of forming the CHA zeolite, and
- (f) a structure directing agent in an amount sufficient to form crystals of the zeolite, wherein the structure directing agent is an N,N,N-trialkyl benzyl quaternary ammonium salt represented general structural formula:
- wherein R1, R2 and R3 are each independently selected from the group consisting of lower alkyl groups, and A− is an anion which is not detrimental to the crystallization of the CHA zeolite;
- and
- (2) heating the reaction mixture under crystallization conditions for sufficient time to form crystals of the CHA zeolite.
7 more elements
Dependencies are inferred from the claim text.