Back to results
US 7,547,810 B2Granted
Coated catalyst for aromatic alkylation
AssigneeCatalytic Distillation Technologies
InventorChristopher C. Boyer
Life of this patent
Estimating the term…
Abstract
A catalyst useful for multi-phase reactors that includes an active component surrounded by a coating on a surface of the active component, wherein the coating provides a liquid film around the active component to increase the useful life of the active component as compared to an uncoated active component.
Claims17
A process for the alkylation of aromatic compounds with olefins comprising:
- contacting aromatic compounds and olefins under conditions of temperature and pressure for alkylation in the presence of a catalyst useful for multi-phase reactors, the catalyst comprising:
- an active component surrounded by an inert, porous coating on a surface of the active component, wherein the inert, porous_coating provides a liquid film around the active component to increase the useful life of the active component as compared to an uncoated active component;
- wherein said inert, porous coating has a pore diameter and contact angle which are selected in conjunction with the surface tension of the liquid to maintain a capillary pressure high enough to prevent the liquid from being displaced by vapor during a two phase flow over the catalyst;
- wherein the capillary pressure is calculated by the formula Pc=2σ cos θ/r;
- where
- Pc is the capillary pressure, psi;
- σ is the surface tension of the liquid, pounds per cubic inch;
- θ is the contact angle of the inert, porous coating in radians;
- and
- r is the radius of the pore, inches.
7 more elements
A process for the alkylation of aromatic compounds with olefins comprising:
- contacting aromatic compounds and olefins under conditions of temperature and pressure for alkylation in the presence of a catalyst useful for multi-phase reactors, the catalyst comprising:
- an active component surrounded by an inert, porous coating on the surface of the active component;
- wherein said inert, porous coating is characterized as having a liquid capillary pressure, calculated by the formula Pc=2σ cos θ/r where
- Pc is the capillary pressure, psi;
- σ is the surface tension of the liquid, pounds per cubic inch;
- θ is the contact angle of the inert, porous coating in radians;
- and
- r is the radius of the pore, inches;
- wherein the capillary pressure as calculated is at least 0.5 psi.
6 more elements
Dependencies are inferred from the claim text.