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US 7,531,698 B2Granted
Tetraphosphorus ligands for catalytic hydroformylation and related reactions
AssigneeThe Penn State Research Foundation
InventorsXumu Zhang, Yongjun Yan
Life of this patent
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Abstract
Tetraphosphorous ligands are combined with transition metal salts to form catalysts for use in hydroformylation, isomerization-hydroformylation, hydrocarboxylation, hydrocyan-ation, isomerization-formylation, hydroaminomethylation and similar related reactions.
Claims8
A phosphorous ligand having the following formula:
- wherein i, j, k, l, m and n are, independently, H, R, Ar, substituted Ar, OR, OAr, COOEt, halide, SO2R, SO3H, SO2NHR, POR2, POAr2 or NR2, where R is an alkyl, substituted alkyl, aryl or substituted aryl and Ar is an aryl;
- X1-X4 are, independently, O, or CH2;
- and Y1, Y′1, Y2, Y′2, Y3, Y′3, Y4, Y′4, are, independently, R, Ar, OR, OAr, pyrrole or substituted pyrrole, or where R, Ar, OR, OAr, pyrrole and substituted pyrrole are linked with a carbon to carbon bond, CH2, NH, NR or O.
Dependencies are inferred from the claim text.