Sodium hydrogencarbonate crystal particles having a low caking property, which comprise sodium hydrogencarbonate crystal particles having an average particle size of from 50 to 500 μm based on the mass, and anhydrous sodium carbonate, and sodium carbonate monohydrate and/or Wegscheider's salt, present on the surface of the sodium hydrogencarbonate crystal particles in such amounts that the total content of anhydrous sodium carbonate, sodium carbonate monohydrate, Wegscheider's salt and sodium sesquicarbonate in the sodium hydrogencarbonate crystal particles is from 0.04 to 1 mass % as calculated as anhydrous sodium carbonate, anhydrous sodium carbonate accounts for at least 40 mass % of the total content, and sodium carbonate monohydrate and/or Wegscheider's salt accounts for from 5 to 60 mass % of the total content.