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US 7,482,113 B2Granted
Photothermographic materials containing co-developers with phosphonium cation
AssigneeCarestream Health, Inc.
InventorsSharon M. Simpson, Kumars Sakizadeh
Life of this patent
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Abstract
Incorporating a combination of a trisphenol reducing agent (developer) and a substituted olefinic co-developer having a phosphonium cation in photothermographic materials improves image tone in resulting images.
Claims20
A photothermographic material comprising a support having on at least one side thereof, one or more photothermographic imaging layers comprising in reactive association:
- a. a photosensitive silver halide,
- b. a non-photosensitive source of reducible silver ions,
- c. a reducing agent composition for said reducible silver ions comprising a trisphenol reducing agent represented by the following Structure (I),
- d. a polymeric binder, and
- e. a substituted olefinic co-developer that is represented by the following Structure (IV):
- wherein L1 and L2 are independently sulfur or a mono-substituted or unsubstituted methylene group,
- R1 and R2 are independently primary or secondary substituted or unsubstituted alkyl groups having 1 to 12 carbon atoms,
- R3, R4, and R5 are independently substituted or unsubstituted alkyl groups having 1 to 12 carbon atoms, substituted or unsubstituted alkoxy groups having 1 to 12 carbon atoms, or halo groups, and
- R6, R7, R8, R9, R10, and R11 are independently hydrogen or any substituent that is substitutable on a benzene ring,
- wherein V and W are independently aromatic or electron withdrawing groups, provided that at least one of V and W is an electron withdrawing group, or V and W can represent the atoms necessary to form a ring containing an electron withdrawing group,
- R is an —O−A+ or —S−A+ group, and
- A+ is a quaternary phosphonium cation.
9 more elements
Dependencies are inferred from the claim text.