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US 7,479,178 B2Granted
Dye sets for inkjet imaging and ink sets using the same
AssigneeHewlett-Packard Development Company, L.P.
InventorsTye J. Dodge, Matthew Thornberry
Life of this patent
Estimating the term…
Abstract
The present invention is directed to dye sets and ink formulated using the same, and in particular dye and ink sets for ink jet printing. The dyes/inks are configured to work in cooperation with one another to produce high quality printed images.
Claims15
An ink set for use as an inkjet ink, comprising:
- a cyan ink including a phthalocyanine compound represented by Formula I;
- a magenta ink including an azo dye represented by Formula III;
- and
- a yellow ink including a yellow dye containing 1,3-naphthalenedisulphonic acid, 7-[[4-[[4,6-bis-[(3-sulfoprop-1-yl)thio]-1,3,5-triazin-2-yl]amino]-3-methoxyphenyl]azo]tetrasodium salt represented by Formula V;
- the cyan ink, the magenta ink, and the yellow ink together exhibiting uniform fade when printed together to form an image;
- wherein Formula I is shown below:
- wherein
- M represents a hydrogen atom, a metal atom;
- or an oxide, hydroxide, or halide thereof;
- and Pc represents a phthalocyanine nucleus;
- wherein R1 and R2 each independently represents a substituent selected from the group consisting of —SOX1, —SO2X1, SO2NX2X3, —SO3X4;
- X1, X2, X3, and X4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group;
- at least one of R1 or R2 has an ionic hydrophilic group as a substituent;
- and
- k and l each independently represents an integer ranging from 1 to 3, provided that k and l each independently is selected such that k+l equals 4;
- and wherein Formula III is shown below:
- wherein
- R21, R23, R25, R27, R29, and R31, are independently selected to be hydrogen atom or sulfonate group;
- R22 is selected to be hydrogen atom or nitro group;
- R26 and R28 are independently selected to be hydrogen atom or methyl group;
- R24 and R30 are independently selected to be a methyl or sulfonate group;
- and
- R32 is selected to be a methyl or methoxy group;
- and wherein Formula V is shown below:
21 more elements
A magenta ink for use as an inkjet ink, comprising:
- a dye represented by Formula III:
- wherein
- R21, R23, R25, R27, R29, and R31, are independently selected to be hydrogen atom or sulfonate group;
- R22 is selected to be hydrogen atom or nitro group;
- R26 and R28 are independently selected to be hydrogen atom or methyl group;
- R24 and R30 are independently selected to be a methyl or sulfonate group;
- and
- R32 is selected to be a methyl or methoxy group;
- and
- a fluorocarbon surfactant formed at least in part from a polymer made based on oxetane chemistry generally being represented by Formula VI and including a pendant perfluoroalkyl group Rf:
- wherein
- Q1 and Q2 are independently selected from the group consisting of H, SO3−W+, COO−W+, and COOH;
- W is selected from the group consisting of NH4, Li, Na, and K;
- R1, R2, R4, and R5 are independently selected from the group consisting of H, OH, O(CH2)m—(CF2)n—CF3 m=1-3 and n=0-3;
- R3 is selected from the group consisting of (CH2)L and
- and
- L=1-4;
- x=1-10;
- y=1-30;
- and z=1-10.
17 more elements
Dependencies are inferred from the claim text.