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US 7,473,812 B2Granted
Method for producing butene oligomers and tert-butyl ethers from C4 flows containing isobutene
AssigneeOxeno Olefinchemie GmbH
InventorsUdo Peters, Dieter Reusch, Andreas Beckmann, Dirk Roettger, Jochen Praefke
Life of this patent
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Abstract
The invention relates to a process for preparing butene oligomers and tert-butyl ethers from C4 hydrocarbon streams, by converting the isobutene to butene oligomers and tert-butyl ethers and removing them from the C4 streams.
Claims10
A process for coproducing butene oligomers and tert-butyl ethers from isobutenic C4 streams by
- a) partly oligomerizing the isobutenic C4 streams over an acidic catalyst to give butene oligomers, and subsequently
- b) etherifying the remaining isobutene with an alcohol under acidic catalysis to give tert-butyl ethers,
- wherein
- the etherification is carried out under acid catalysis in stage b) in at least two reaction stages, of which at least the last reaction stage is carried out as a reactive distillation, and the butene oligomers obtained in stage a) are removed before the acid-catalyzed etherification in stage b).
1 more element
Dependencies are inferred from the claim text.