# US 7,465,429 B2 · Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same

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- Number: US 7,465,429 B2
- Document ID: US7465429B2
- Status: Granted
- Kind: B2
- Application number: 10/081,208
- Filed: 2002-02-25
- Published: 2002-09-19
- Granted: 2008-12-16
- Earliest claimed: 1995-10-02
- Assignees: Osaka Gas Co., Ltd.; Mitsubishi Jukogyo Kabushiki Kaisha
- Inventors: Isao Mochida; Akinori Yasutake; Toshihiko Setoguchi; Norihisa Kobayashi; Takahiro Kasuh; Masaaki Yoshikawa
- Web page: https://patentgrep.com/patent/US7465429B2

## CPC

- B01J 21/18: Carbon
- B01D 53/8628: {Processes characterised by a specific catalyst}
- B01D 2255/702: Carbon
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)

## Abstract

This invention relates to a technique for removing nitrogen oxides (NOx) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100° C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100° C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600. to 1,200° C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.

## Claims

### Claim 1

A denitration system comprising
(A) a first reactor that has an inlet and an outlet and that is packed with a heat treated active carbon having an atomic surface oxygen/surface carbon ratio of 0.05 or less;
(B) a second reactor that has an inlet and an outlet and that is packed with said heat treated active carbon, wherein the outlet of the first reactor is connected to the inlet of the second reactor;
(C) an ammonia supply line that is connected the inlet of said first reactor;
(D) a system inlet that is connected to the inlet of said first reactor; and
(E) a system outlet that is connected to the outlet of the second reactor.

### Claim 2 (depends on 1)

The denitration system of claim 1, wherein the heat treated active carbon is a heat treated carbon fiber.

### Claim 3

A denitration system comprising
(A) a first reactor that has an inlet and an outlet and that is packed with a heat treated active carbon having an atomic surface oxygen/surface carbon ratio of 0.05 or less;
(B) a second reactor that has an inlet and an outlet and that is packed with said heat treated active carbon;
(C) an ammonia supply line that is connected to the inlet of the first reactor through a first valve and to the inlet of the second reactor through a second valve;
(D) a system inlet that is connected to the inlet of the first reactor through the first valve and to the inlet of the second reactor through the second valve; and
(E) an outlet of the denitration system, wherein
(i) the outlet of the first reactor is connected to the inlet of the second reactor through the third valve and to the system outlet through the fourth valve,
(ii) the outlet of the second reactor is connected to the system outlet through the fifth valve and the inlet of the first reactor through the sixth valve, and
(iii) if the first, third and fifth valves are open, the second, fourth and sixth valves are closed, and if the first, third and fifth valves are closed, the second, fourth and sixth valves are open.

### Claim 4 (depends on 3)

The denitration system of claim 3, wherein the heat treated active carbon is a heat treated carbon fiber.

### Claim 5

A denitration system comprising
(A) a denitrator that has an inlet and an outlet and that is packed with a heat treated active carbon having an atomic surface oxygen/surface carbon ratio of 0.05 or less;
(B) a first NH3 adsorber that has an inlet and an outlet;
(C) a second NH3 adsorber that has an inlet and an outlet;
(D) a first ammonia supply line;
(E) a second ammonia supply line;
(F) a system inlet; and
(G) a system outlet, wherein
(i) the system inlet is connected to the inlet of the first adsorber via a first valve and to the outlet of the second adsorber through the second valve;
(ii) the first ammonia supply line is connected to both the inlet of the denitrator and the outlet of the first adsorber through a third valve;
(iii) the second ammonia supply line is connected to both the outlet of the denitrator and the inlet of the second adsorber through a fourth valve;
(iv) the inlet of the denitrator is connected to the outlet of the first ads orber;
(v) the outlet of the denitrator is connected to the inlet of the second adsorber;
(vi) the outlet of the second adsorber is connected to the system outlet through a fifth valve;
(vii) the inlet of the first adsorber is connect to the system outlet through a sixth valve; and
(viii) if the first, third and fifth valves are open, the second, fourth and sixth valves are closed, and if the first, third and fifth valves are closed, the second, fourth and sixth valves are open.

### Claim 6 (depends on 5)

The denitration system of claim 5, wherein the heat-treated active carbon is a heat treated carbon fiber.