Phase change solvents for thermoplastic elastomers
AssigneeThe Procter & Gamble Company
InventorsMark William Hamersky, Steven Daryl Smith
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Abstract
Novel elastomeric compositions that contain at least one thermoplastic elastomer and at least one phase change solvent. Above the phase change temperature, the phase change solvent solubilizes or intimately mixes with the thermoplastic elastomers. Below the phase change temperature, the phase change solvent solidifies or crystallizes within the thermoplastic matrix. The phase change behavior of these materials produce elastomeric compositions that exhibit lowered viscosity and lowered processing temperature without substantially compromising the mechanical properties. The present invention also relates a method of lowering the viscosity and improving the processability of a thermoplastic elastomer using the phase change solvent.
Claims24
A composition comprising:
- a) from about 1 to about 99 wt % a thermoplastic elastomer, which is a block copolymer having at least one soft block and at least one hard block;
- b) from about 1 to about 70 wt % a phase change solvent having the general formula:
- R′—Py-(Q-Px)n−2-Q-Py—R;
- (I)
- R′—Py-(Q-Px)n—R;
- (II)
- R′-(Q-Px)n—R;
- (III)
- R′-(Q-Px)n−1-Q-Py—R;
- (IV)
- R′-(Q-Px)n−1-Q-R;
- or (V)
- mixtures thereof;
- (VI)
- wherein Q is a para-ring substituted difunctional aromatic moiety, and wherein the substitutions are in the 1,4 positions;
- P is CH2;
- R and R′ are the same or different and are independently selected from H, CH3, COOH, CONHR1, CONR1R2, NHR3, NR3R4, hydroxyl, or C1-C30 alkoxy;
- wherein R1, R2, R3 and R4 are the same or different and are independently selected from H or linear or branched alkyl from C1-C30;
- x is an integer from 1 to 30;
- y is an integer from 1 to 30;
- and n is an integer from 3 to 7;
- wherein the phase change solvent has a phase change in a temperature range from about 40° C. to about 250° C.
Dependencies are inferred from the claim text.