Catalyst for acid-catalyzed by hydrocarbon conversions
AssigneeSud-Chemie AG
InventorsJohannes A. Lercher, Andreas Feller, Stefan Gaab
Life of this patent
Estimating the term…
Loading patent…
AssigneeSud-Chemie AG
InventorsJohannes A. Lercher, Andreas Feller, Stefan Gaab
Estimating the term…
A catalyst for acid-catalyzed hydrocarbon conversions, in particular for the alkylation of olefins with isoparaffins, containing a crystalline zeolite with an SiO2—Al2O3 molar ratio of <10, the alkali cations of which are at least partially replaced by H+ ions and/or polyvalent cations, the residual concentration of alkali cations amounting to less than around 0.2% by weight, the concentration of the Bronsted centers, determined as a function of the pyridine chemisorbed on the catalyst surface, amounting to around 0.1 to 4 mmol/g of catalyst, and the ratio between the concentration of the acid centers of the Bronsted type (B) and of the Lewis type (L), expressed as the surface ratio of the absorption bands at 1540 ±5 cm−1 (B) and 1450 5 cm−1 (L) after heating to a temperature of 450° C amounting to around 1.4 or higher, is described.
A catalyst for acid-catalyzed hydrocarbon conversions, in particular for the alkylation of olefins with isoparaffins, comprising a crystalline faujasite of the X, Y or LSX type with an SiO2-Al2O3 molar ratio of <10, wherein alkali cations are at least partially replaced with trivalent or polyvalent cations, wherein the residual concentration of alkali cations is less than about 0.2% by weight, wherein the concentration of Bronsted acid sites, determined as a function of pyridine chemisorbed on the catalyst surface, comprises about 0.1 to 4 mmol/g of catalyst, and wherein the ratio between the concentration of the acid sites of the Bronsted type (B) and of Lewis type (L), expressed as a surface ratio of absorption bands at 1540 ±5 cm−1 (B) and 1450 ±5 cm−1 (L) after heating to a temperature of 450° C is about 1.4 or higher, wherein the portion of the pyridine not yet desorbed from the catalyst surface at a temperature of 450° C which is bonded to the Bronsted acid sites comprises about 30 to 60 wt % of the pyridine chemisorbed at the Bronsted acid sites at 100° C.
Dependencies are inferred from the claim text.