Resist composition and patterning process using the same
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsJun Hatakeyama, Youichi Ohsawa, Seiichiro Tachibana
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Abstract
There is disclosed a resist composition which comprises, at least, a polymer in which a sulfonium salt having a polymerizable unsaturated bond, a (meth)acrylate having a lactone or a hydroxyl group as an adhesion group, and a (meth)acrylate having an ester substituted with an acid labile group are copolymerized. There can be provided a resist composition with high resolution which has high sensitivity and high resolution to high energy beam, especially to ArF excimer laser, F2 excimer laser, EUV, X-ray, EB, etc., has reduced line edge roughness, and comprises a polymeric acid generator which has insolubility in water, and sufficient thermal stability and preservation stability.
Claims12
A resist composition comprising a polymer in which:
- a sulfonium salt having a polymerizable unsaturated double bond,
- a (meth)acrylate having a lactone or a hydroxyl group as adhesion group, and
- a (meth)acrylate having an ester substituted with an acid labile group are copolymerized;
- wherein the repeating unit formed from the sulfonium salt having a polymerizable unsaturated bond is represented by the following general formula (1)
- where:
- R1 represents a hydrogen atom or a methyl group,
- R2 represents any one of:
- —O—R6—,
- —C(═O)—X1—R6—,
- —C(═O)—O—C2H4—O—Y1—,
- —C(═O)—O-Z1-C(═O)—CH2—,
- —Z1—C(═O)—CH2—,
- —C(═O)—O—Z1—CH2—,
- —C(═O)—O—CH2—C(═O)—O—Z1-, and
- —C(═O)—O—C2H4—C(═O)—O—Z1-,
- where:
- X1 represents an oxygen atom or NH,
- R6 represents a linear, branched or cyclic alkylene group having 1-6 carbon atoms or a phenylene group which may contain a carbonyl group, an ester group or an ether group,
- Y1 represents any one of a phenylene group, a naphthylene group, and an anthrylene group, and
- Z1 represents a phenylene group,
- R3 and R4 each independently represents:
- a linear, branched or cyclic alkyl group having 1-12 carbon atoms which may contain a carbonyl group, an ester group or an ether group,
- an aryl group having 6-12 carbon atoms,
- an aralkyl group having 7-20 carbon atoms or a thiophenyl group, or
- R3 and R4 may bond each other to form a ring, and
- R5 represents a perfluoro-4-ethylcyclohexyl group.
Dependencies are inferred from the claim text.