Functional fluids containing alkylene oxide copolymers having low pulmonary toxicity
AssigneeBASF SE
InventorsJohn V. Sherman, Ludwig Voelkel, Marc Walter, Christian Wulff, Michael Stoesser, Siegbert Brand
Life of this patent
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Abstract
The invention relates to a method of reducing the inhalation toxicity of functional fluids by incorporating into a functional fluid an effective amount of copolymer which is obtainable by copolymerizing etheylene oxide, propylene oxide and/or butylenes oxide with an initiator monool or diol, said copolymer having a degree of unsaturation of less than about 0.01 meq/g.
Claims32
A method of reducing the inhalation toxicity of functional fluids, comprising:
- incorporating into a functional fluid an effective amount of a copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units.
A functional fluid comprising
- a) 65-95 wt % of the copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units;
- b) 3-20 wt % emulsifiers;
- c) 0-5 wt % antistatic agents;
- d) 0-5 wt % corrosion inhibitors;
- e) 0-5 wt % further additives;
- wherein said functional fluid is a low inhalation toxicity lubricant for fiber production.
A functional fluid comprising
- a) 75-98 wt % of a copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units;
- b) 0-5 wt % metal passivators;
- c) 0-5 wt % antioxidants;
- d) 0-5 wt % corrosion inhibitors;
- e) 0-5 wt % antiwear and extreme pressure additives;
- f) 0-5 wt % further additives;
- wherein said functional fluid is a low inhalation toxicity hydraulic fluid or a low inhalation toxicity gear lubricant, or a low inhalation toxicity compressor lubricant, or a low inhalation toxicity refrigeration lubricant, or a low inhalation toxicity mill and calender lubricant.
A functional fluid comprising
- a) 30-60 wt % of a copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units;
- b) 0-40 wt % glycols;
- c) 20-45 wt % water;
- d) 0-15 wt % polyalkylene thickener;
- e) 0-5 wt % metal passivators;
- f) 0-5 wt % antioxidants;
- g) 0-5 wt % corrosion inhibitors;
- h) 0-5 wt % boundary lubricants;
- wherein the functional fluid is a low inhalation toxicity water glycol hydraulic fluid.
A functional fluid comprising
- a) 25-55 wt % of a copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units;
- b) 35-65 wt % water;
- c) 5-26 wt % metal passivators and corrosion inhibitors;
- d) 0-5 wt % antioxidants;
- e) 0-5 wt % antiwear and extreme pressure additives;
- f) 0-5 wt % further additives;
- wherein the functional fluid is a low inhalation toxicity water soluble metalworking fluid.
A functional fluid comprising
- a) 50-99 wt % of a copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units;
- b) 0-30 wt % glycol ethers;
- c) 0-20 wt % glycols;
- d) 0-5 wt % metal passivators;
- e) 0-5 wt % antioxidants;
- f) 0-5 wt % corrosion inhibitors;
- g) 0-5 wt % antiwear and extreme pressure additives;
- h) 0-5 wt % further additives;
- wherein the functional fluid is a low inhalation toxicity DOT 3 brake fluid.
A functional fluid comprising
- a) 85-98 wt % of a copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units;
- b) 0-5 wt % metal passivators;
- c) 0-5 wt % antioxidants;
- d) 0-5 wt % corrosion inhibitors;
- e) 0-5 wt % detergents;
- f) 0-5 wt % antiwear and extreme pressure additives;
- g) 0-5 wt % further additives;
- wherein the functional fluid is a low inhalation toxicity 4-stroke engine lubricant or a low inhalation toxicity 2-cycle engine lubricant or a low inhalation toxicity universal transmission lubricant.
A functional fluid comprising
- a) 90-99 wt % of a copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units;
- b) 0-5 wt % antioxidants;
- c) 0-5 wt % further additives;
- wherein the functional fluid is a low inhalation toxicity mandrel or mold release lubricant for processing of rubber based elastomers.
A functional fluid comprising
- a) 5-35 wt % of a copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units;
- b) 65-95 wt % water,
- c) 0-5 wt % corrosion inhibitors;
- d) 0-5 wt % further additives;
- wherein the functional fluid is a low inhalation toxicity quenchant.
A functional fluid comprising
- a) 40-85 wt % of a copolymer which is obtainable by copolymerizing ethylene oxide, propylene oxide and/or butylene oxide with a monool initiator, said copolymer having a degree of unsaturation of less than about 0.01 meq/g, wherein the monool initiator is n-butanol or a polyoxyalkylene monoether thereof containing from 1 to 20 oxyalkylene units;
- b) 0-45 wt % butanol initiated polypropylene glycol;
- c) 5-15 wt % thickeners;
- d) 0-5 wt % metal passivators;
- e) 0-5 wt % antioxidants;
- f) 0-5 wt % corrosion inhibitors;
- g) 0-5 wt % antiwear and extreme pressure additives;
- h) 0-5 wt % further additives;
- wherein the functional fluid is a low inhalation toxicity grease lubricant.
Dependencies are inferred from the claim text.