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US 7,452,949 B2Granted
Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins
AssigneeBasell Polyolefine GmbH
InventorsYoshikuni Okumura, Ilya Nifant'ev, Michael J. Elder, Pavel V. Ivchenko, Vladimir V. Bagrov
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Abstract
The present invention relates to organometallic transition metal compounds of the formula (I)
Claims9
An organometallic transition metal compound of the formula (I):
- where
- M1 is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements or the lanthanides;
- the radicals X are identical or different and are each an organic or inorganic radical, with two radicals X also being able to be joined to one another;
- m is 1 or 2;
- n is a natural number from 1 to 4;
- R1 is hydrogen or an organic radical having from 1 to 40 carbon atoms;
- R3 is a substituted or unsubstituted C6-C40 aryl radical;
- R4 is hydrogen, halogen or an organic radical having from 1 to 40 carbon atoms;
- R5 is an organic radical which has from 3 to 20 carbon atoms and is branched in the α position;
- R7, R8 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms or R7 and R8 together with the atoms connecting them form a monocyclic or polycyclic, substituted or unsubstituted ring system which has from 1 to 40 carbon atoms and optionally contains heteroatoms selected from the group consisting of the elements Si, Ge, N, P, O, S, Se and Te;
- and
- A is a bridge consisting of a divalent atom or a divalent group.
9 more elements
A biscyclopentadienyl ligand system of the formula (II):
- or its double bond isomers,
- wherein
- m is 1 or 2;
- R1 is hydrogen or an organic radical having from 1 to 40 carbon atoms;
- R3 is a substituted or unsubstituted C6-C40 aryl radical;
- R4 is hydrogen, halogen or an organic radical having from 1 to 40 carbon atoms;
- R5 is an organic radical which has from 3 to 20 carbon atoms and is branched in the α position;
- R7, R8 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms or R7 and R8 together with the atoms connecting them form a monocyclic or polycyclic, substituted or unsubstituted ring system which has from 1 to 40 carbon atoms and optionally contains heteroatoms selected from the group consisting of the elements Si, Ge, N, P, O, S, Se and Te;
- and
- A is a bridge consisting of a divalent atom or a divalent group.
7 more elements
Dependencies are inferred from the claim text.