Optical glass and optical product using the same
AssigneeHoya Corporation
InventorsXuelu Zou, Hiromasa Tawarayama, Kazutaka Hayashi, Hiroshi Kawazoe
Life of this patent
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Abstract
An optical glass having a high refractive index and high dispersion characteristics that is suited to application to precision press molding to precisely mold the shape of final products for objectives not requiring grinding or polishing. An optical glass exhibiting a refractive index in the range of from 1.75 to 2.0, an Abbé number in the range of from 20 to 28.5. Optical parts comprised of this glass; press-molding materials comprised of this glass; methods of manufacturing the same; and methods of manufacturing molded glass products employing these materials.
Claims4
A method of manufacturing glass products comprising heating a press-moldable glass perform;
- and precisely press molding the heated glass perform to obtain a glass product, wherein said glass perform is prepared by the method wherein a prescribed amount of a piece of molten optical glass flowing out of a flowout pipe is received in a receiving mold to prepare a glass perform, wherein the optical glass exhibits a refractive index in the range of from 1.75 to 2.0, an Abbé number in the range of from 20 to 28.5, and a viscosity at the liquid phase temperature equal to or higher than 0.4 Pa·s, wherein said optical glass comprises, as molar percentages:
- 12-34 percent of P2O5;
- 0.2-15 percent of B2O3, where the total quantity of P2O 5 and B2O3 is 15-35 percent;
- 2-40 percent of WO3;
- 0-25 percent (excluding 0 percent) of Nb2O5;
- 0 to 10 percent (excluding 0 percent) of TiO2, where the total quantity of WO3, Nb2O5 and TiO2 is 20-45 percent;
- 0-25 percent (excluding 0 percent) of BaO;
- 0-20 percent (excluding 0 percent) of ZnO, where the total quantity of BaO and ZnO is less than 30 percent;
- 2-30 percent of Li2O;
- 2-30 percent of Na2O;
- 0-15 percent (excluding 0 percent) of K2O, where the total quantity of Li2O, Na2O, and K2O is 29-45 percent;
- 0-10 percent of CaO;
- 0-10 percent of SrO;
- 0-5 percent of Al2O3;
- 0-5 percent of Y2O3;
- 0-1 percent of Sb2O3;
- and
- 0-1 percent of As2O3, where the total quantity of all of the above-listed components is equal to or more than 94 percent;
- and
- wherein said optical glass comprises, as essential components, P2O5, B2O3, WO3, Nb2O5, TiO2, BaO, ZnO, Li2O, Na2O and K2O, and does not comprise an amount of GeO2.
A method of manufacturing glass products comprising heating a press-moldable glass perform;
- and precisely press molding the heated glass perform to obtain a glass product, wherein said glass perform is prepared by the method wherein a prescribed amount of a piece of molten optical glass flowing out of a flowout pipe is received in a receiving mold to prepare a glass perform, wherein the optical glass exhibits a refractive index in the range of from 1.75 to 2.0, an Abbé number in the range of from 20 to 28.5, and a viscosity at the liquid phase temperature equal to or higher than 0.4 Pa·s, wherein said optical glass comprises, as molar percentages:
- 12-34 percent of P2O5;
- 0.2-15 percent of B2O3, where the total quantity of P2O 5 and B2O3 is 15-35 percent;
- 2-40 percent of WO3;
- 0-25 percent (excluding 0 percent) of Nb2O5;
- 0 to 10 percent (excluding 0 percent) of TiO2, where the total quantity of WO3, Nb2O5 and TiO2 is 20-45 percent;
- 0-11 percent (excluding 0 percent) of BaO;
- 0-20 percent (excluding 0 percent) of ZnO, where the total quantity of BaO and ZnO is less than 30 percent;
- 2-30 percent of Li2O;
- 2-30 percent of Na2O;
- 0-15 percent (excluding 0 percent) of K2O, where the total quantity of Li2O, Na2O, and K2O is 10-45 percent;
- 0-10 percent of CaO;
- 0-10 percent of SrO;
- 0-5 percent of Al2O3;
- 0-5 percent of Y2O3;
- 0-1 percent of Sb2O3;
- and
- 0-1 percent of As2O3, where the total quantity of all of the above-listed components is equal to or more than 94 percent;
- and
- wherein said optical glass comprises, as essential components, P2O5, B2O3, WO3, Nb2O5, TiO2, BaO, ZnO, Li2O, Na2O and K2O, and does not comprise an amount of GeO2.
Dependencies are inferred from the claim text.