Rubber composition comprising a citraconimidomaleimide
AssigneeMichelin Recherche et Technique S.A.
InventorsJosé Carlos Araujo Da Silva, Laure Belin, Christiane Blanchard
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Abstract
A rubber composition, usable for the manufacture of tires, is based on at least one diene elastomer, reinforcing filler, vulcanization system and, as anti-reversion agent, a citraconimidomaleimide compound of the formula (R=hydrocarbon radical): The composition may be used for the manufacture of a finished article or a semi-finished product made of rubber intended for a ground contact system of an automobile, in particular of a tire.
Claims32
A rubber composition usable for the manufacture of tires, based on at least one diene elastomer, at least one reinforcing filler, a vulcanization system and at least one maleimide compound, wherein said maleimide compound is a citraconimidomaleimide of the formula (R=radical consisting of carbon, hydrogen and optionally one or more heteroatoms selected from the group consisting of O, N and S):
A process for preparing a rubber composition usable for the manufacture of tires and having an improved reversion resistance, this composition being based on at least one diene elastomer, at least one reinforcing filler and a vulcanization system, said process comprising:
- incorporating in a diene elastomer, during a first step referred to as “non-productive”, at least one reinforcing filler, by thermomechanically kneading the entire mixture, in one or more stages, until a maximum temperature of between 110° C. and 190° C. is reached;
- cooling the entire mixture to a temperature of less than 100° C.;
- then incorporating, during a second step referred to as “productive”, the vulcanization system;
- and
- kneading the entire mixture until a maximum temperature of less than 110° C. is reached,
- wherein there is further incorporated, during any one of the steps of the process, at least one citraconimidomaleimide compound of the formula (I) (R=radical consisting of carbon, hydrogen and optionally one or more heteroatoms selected from the group consisting of O, N and S):
Dependencies are inferred from the claim text.