Oxidation catalysts comprising metal exchanged hexaaluminate wherein the metal is Sr, Pd, La, and/or Mn
AssigneeTDA Research, Inc.
InventorsDavid Wickham, Ronald Cook
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AssigneeTDA Research, Inc.
InventorsDavid Wickham, Ronald Cook
Estimating the term…
The present invention provides metal-exchanged hexaaluminate catalysts that exhibit good catalytic activity and/or stability at high temperatures for extended periods with retention of activity as combustion catalysts, and more generally as oxidation catalysts, that make them eminently suitable for use in methane combustion, particularly for use in natural gas fired gas turbines. The hexaaluminate catalysts of this invention are of particular interest for methane combustion processes for minimization of the generation of undesired levels (less than about 10 ppm) of NOx species. Metal exchanged hexaaluminate oxidation catalysts are also useful for oxidation of volatile organic compounds (VOC), particularly hydrocarbons. Metal exchanged hexaaluminate oxidation catalysts are further useful for partial oxidation, particularly at high temperatures, of reduced species, particularly hydrocarbons (alkanes and alkenes).
An oxidation catalyst which comprises a metal exchanged hexaaluminate, prepared by metal exchange of an alumoxane precursor, having the formula:
An oxidation catalyst which comprises a metal exchanged hexaaluminate, substituted with three metals, La, Sr and Mn, and prepared by metal exchange of an alumoxane precursor, having the formula:
Dependencies are inferred from the claim text.