Poly etch without separate oxide decap
AssigneeMicron Technology, Inc.
InventorKevin Shea
Life of this patent
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Abstract
The use of an ammonium hydroxide spike to a hot tetra methyl ammonium hydroxide (TMAH) solution to form an insitu poly oxide decapping step in a polysilicon (poly) etch process, results in a single step rapid poly etch process having uniform etch initiation and a high etch selectivity, that may be used in manufacturing a variety of electronic devices such as integrated circuits (ICs) and micro electro-mechanical (MEM) devices. The etching solution is formed by adding 35% ammonium hydroxide solution to a hot 12.5% TMAH solution at about 70° C. at a rate of 1% by volume, every hour. Such an etch solution and method provides a simple, inexpensive, single step self initiating poly etch that has etch stop ratios of over 200 to 1 over underlying insulator layers and TiN layers.
Claims25
A method of forming a patterned polysilicon layer in a single chemical etch solution, comprising:
- exposing a substrate having a photo-resist pattern on a polysilicon layer to a liquid chemical etch solution containing at least tetra methyl ammonium hydroxide and water at a preselected temperature and first concentration;
- adding an ammonium hydroxide solution at approximately the same time as exposing the substrate;
- and
- removing the substrate from the etch solution after a preselected time period.
A method of etching polysilicon, comprising:
- adding a first volume of an ammonium hydroxide solution to a second volume of a tetra methyl ammonium hydroxide solution;
- immersing at least one surface of a polysilicon layer having a patterned photo-resist mask in the ammonium hydroxide and tetra methyl ammonium hydroxide solution within a specified time period after adding the ammonium hydroxide solution, the solution having a preselected temperature;
- and
- removing the polysilicon layer after a preselected time period.
Dependencies are inferred from the claim text.