# US 7,411,105 B2 · Process and installation for the oligomerization of olefins that use a membrane separation

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- Number: US 7,411,105 B2
- Document ID: US7411105B2
- Status: Granted
- Kind: B2
- Application number: 11/639,307
- Filed: 2006-12-15
- Published: 2007-04-19
- Granted: 2008-08-12
- Earliest claimed: 2005-04-11
- Assignees: Institut Francais du Petrole
- Inventors: Alain Forestiere; Frederic Favre; Arnaud Baudot; Laurent Bournay
- Web page: https://patentgrep.com/patent/US7411105B2

## CPC

- C07C 2/30: containing metal-to-carbon bond; Metal hydrides
- C07C 2/24: with metals
- C07C 7/144: using membranes, e.g. selective permeation
- Y02P 20/582: Recycling of unreacted starting or intermediate materials
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

This invention relates to a process for the oligomerization of olefins that have 2 to 6 carbon atoms comprising at least: a) One reaction stage in which a first effluent that comprises oligomers, paraffins and olefins that have not reacted is recovered, b) A separation stage that makes it possible to separate a portion of the oligomers that are contained in the effluent from a mixture that comprises oligomers, paraffins and the olefins that have not reacted, c) A recycling of a portion of said mixture in the reaction stage, and d) A stage for membrane separation of another portion of said mixture so as to draw off a permeate that comprises at least 70% by weight of olefins and a retentate that comprises paraffins and oligomers, e) A stage for recovery of oligomers on the retentate.

## Claims

### Claim 1

Process for the oligomerization of olefins that have 2 to 6 carbon atoms, comprising at least:
a) One reaction stage in which a first effluent that comprises oligomers, paraffins and olefins that have not reacted is recovered,
b) At least one separation stage that makes it possible to separate a portion of the oligomers that are contained in the effluent from a mixture that comprises oligomers, paraffins and the olefins that have not reacted,
c) Recycling of a portion of said mixture in the reaction stage, and
d) A stage for membrane separation of another portion of said mixture so as to draw off a permeate that comprises at least 70% by weight of olefins and a retentate that comprises paraffins and oligomers,
e) At least one stage for separation of at least one portion of the oligomers from said retentate.

### Claim 2 (depends on 1)

Process according to claim 1, in which between 15% and 95% by weight of the oligomers contained in the supply of the membrane separation stage are recovered in stage e).

### Claim 3 (depends on 2)

Process according to claim 2, in which the olefins are acyclic monoolefins with 2 to 6 carbon atoms, pure or in a mixture.

### Claim 4 (depends on 3)

Process according to claim 3, in which the olefins are essentially ethylene.

### Claim 5 (depends on 3)

Process according to claim 3, in which the olefines are essentially propylene.

### Claim 6 (depends on 3)

Process according to claim 3, in which the olefins are essentially a mixture of ethylene and propylene.

### Claim 7 (depends on 1)

Process according to claim 1, in which the catalyst that is used for carrying out the reaction stage a) comprises a transition metal.

### Claim 8 (depends on 1)

Process according to claim 1, in which the catalyst that is used in stage a) is a catalyst that is homogeneous with regard to the reaction medium and comprises one or more transition metals of groups 4, 5, 6, 7, 8, 9, 10, 11 or 12 of the periodic table.

### Claim 9 (depends on 1)

Process according to claim 1, in which the reaction temperature of stage a) is between 0 and 300° C.

### Claim 10 (depends on 1)

Process according to claim 1, in which the pressure of stage a) is between the atmospheric pressure (0.1 MPa) and 35 MPa.

### Claim 11 (depends on 1)

Process according to claim 1, in which the membranes that are used are vitreous rigid polymers.

### Claim 12 (depends on 1)

Process according to claim 1, in which the membranes are used in “gas/vapor permeation” mode.

### Claim 13 (depends on 1)

Process according to claim 1, in which the separation stage e) that makes it possible to separate the oligomers from the paraffins is carried out by condensation.

### Claim 14 (depends on 1)

Process according to claim 1, in which the permeate is recycled in the reaction stage.