# US 7,411,085 B2 · Carbon nanotube dispersion, production method of carbon nanotube structure and carbon nanotube structure

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- Number: US 7,411,085 B2
- Document ID: US7411085B2
- Status: Granted
- Kind: B2
- Application number: 11/723,652
- Filed: 2007-03-21
- Published: 2008-05-01
- Granted: 2008-08-12
- Earliest claimed: 2006-09-29
- Assignees: Fuji Xerox Co., Ltd.
- Inventors: Masaki Hirakata; Taishi Shigematsu
- Web page: https://patentgrep.com/patent/US7411085B2

## CPC

- C01B 32/174: Derivatisation; Solubilisation; Dispersion in solvents
- B82Y 30/00: Nanotechnology for materials or surface science, e.g. nanocomposites
- B82Y 40/00: Manufacture or treatment of nanostructures
- B05D 2401/32: applied as powders
- C01B 2202/02: Single-walled nanotubes
- C01B 2202/28: Solid content in solvents
- Y10S 977/788: Of specified organic or carbon-based composition
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B05D: PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL (conveying articles or workpieces through baths of liquid B65G, e.g. B65G49/02)
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

A carbon nanotube dispersion includes a carbon nanotube compound represented by structural formula A and a dispersion medium in which the carbon nanotube is dispersed or dissolved, wherein a moiety represented by double lines represents a carbon nanotube R1 represents a hydrogen atom, a substituted or unsubstituted alkyl group having one or two carbon atoms, a substituted or unsubstituted aryl group or a substituted or unsubstituted carbodiimide group, R2 represents a substituted or unsubstituted alkyl group having from 1 to 4 carbon atoms, and m and n each independently represents an integer of 1 or more.

## Claims

### Claim 1

A carbon nanotube dispersion comprising:
a carbon nanotube compound represented by structural formula A; and
a dispersion medium in which the carbon nanotube is dispersed or dissolved,
wherein a moiety represented by double lines represents a carbon nanotube;
R1 represents a hydrogen atom, a substituted or unsubstituted alkyl group having one or two carbon atoms, a substituted or unsubstituted aryl group or a substituted or unsubstituted carbodiimide group;
R2 represents an unsubstituted alkyl group having from 1 to 4 carbon atoms; and
m and n each independently represents an integer of 1 or more.

### Claim 2 (depends on 1)

The carbon nanotube dispersion according to claim 1, further comprising:
a crosslinking agent that crosslinks the carbon nanotube compounds by chemically bonding functional groups containing R1 in structural formula A to each other.

### Claim 3 (depends on 1)

The carbon nanotube dispersion according to claim 1,
wherein R1 in structural formula A is a substituted or unsubstituted alkyl group having one or two carbon atoms.

### Claim 4 (depends on 1)

The carbon nanotube dispersion according to claim 1,
wherein the dispersion medium acts also as a crosslinking agent for crosslinking the carbon nanotube compounds by chemically bonding functional groups containing R1 in structural formula A to each other.

### Claim 5 (depends on 1)

The carbon nanotube dispersion according to claim 1,
wherein the carbon nanotube in the structural formula A is a single-walled carbon nanotube.

### Claim 6

A production method of a carbon nanotube structure comprising:
preparing a carbon nanotube dispersion, wherein the preparing comprises dispersing or dissolving at least a carbon nanotube compound represented by structural formula A in a dispersion medium; and
supplying the carbon nanotube dispersion onto a surface of a substrate,
wherein a moiety represented by double lines represents a carbon nanotube;
R1 represents a hydrogen atom, a substituted or unsubstituted alkyl group having one or two carbon atoms, a substituted or unsubstituted aryl group or a substituted or unsubstituted carbodiimide group;
R2 represents an unsubstituted alkyl group having from 1 to 4 carbon atoms; and
m and n each independently represents an integer of 1 or more.

### Claim 7 (depends on 6)

The production method of the carbon nanotube structure according to claim 6,
wherein the preparing comprises adding a crosslinking agent that crosslinks the carbon nanotube compounds by chemically bonding functional groups containing R1 in structural formula A to each other.

### Claim 8 (depends on 7)

The production method of the carbon nanotube structure according to claim 7,
wherein R1 in structural formula A is a substituted or unsubstituted alkyl group having one or two carbon atoms.

### Claim 9 (depends on 6)

The production method of the carbon nanotube structure according to claim 6,
wherein the dispersion medium acts also as a crosslinking agent for crosslinking the carbon nanotube compounds by chemically bonding functional groups containing R1 in structural formula A to each other.

### Claim 10 (depends on 6)

The production method of the carbon nanotube structure according to claim 6,
wherein the carbon nanotube in structural formula A is a single-walled carbon nanotube.

### Claim 11 (depends on 6)

The production method of a carbon nanotube structure according to claim 6, further comprising:
crosslinking the carbon nanotube compounds by chemically bonding functional groups containing R1 in structural formula A to each other after the supplying the carbon nanotube dispersion onto the surface of the substrate.

### Claim 12 (depends on 6)

The production method of a carbon nanotube structure according to claim 6,
wherein the dispersion medium comprises at least one of water and a water-soluble solvent at the preparing the dispersion; and
the substrate at supplying the carbon nanotube dispersion is a substrate having a hydrophilic surface or a substrate having a hydrophilicization-processed surface.

### Claim 13

A carbon nanotube structure comprising:
a carbon nanotube compound represented by structural formula B,
wherein a moiety represented by double lines represents a carbon nanotube;
X represents OR1 or a crosslinking site, wherein R1 represents a hydrogen atom, a substituted or unsubstituted alkyl group having one or two carbon atom(s), a substituted or unsubstituted aryl group or a substituted or unsubstituted carbodiimide group and the crosslinking site are crosslinked to a carbonyl group in other carbon nanotube compounds represented by structural formula B;
R2 represents an unsubstituted alkyl group having from 1 to 4 carbon atom(s); and
m and n each independently represents an integer of 1 or more.

### Claim 14 (depends on 13)

The carbon nanotube structure according to claim 13,
wherein X represents the crosslinking site;
the crosslinking site has a chemical structure selected from the group consisting of —O—, —O(CH2)2O—, —OCH2CHOHCH2O—, —OCH2CH(CH2OH)O— and a following structure; and
the carbon nanotube structure has a network structure of the carbon nanotubes.

### Claim 15 (depends on 13)

The carbon nanotube structure according to claim 13,
wherein the carbon nanotube in structural formula B is a single-walled carbon nanotube.
